Mailing Address
Dr. Xiang-Zhao Kong
Geothermal Energy & Geofluids
Institute of Geophysics
NO F 57
Sonneggstrasse 5
CH-8092 Zurich Switzerland
Contact
| Phone | +41 44 632 55 86 |
| xkong(at)ethz.ch |
Administration
| Prisca Maurantonio | |
| +41 44 632 3465 | |
| prisca.maurantonio@eaps.ethz.ch | |
Publications
[Go to Proceedings Refereed] [Go to Proceedings Non-Refereed] [Go to Theses]
Underlined names are links to current or past GEG members
REFEREED PUBLICATIONS IN JOURNALS
54.
Yevugah, Y., X.-Z. Kong, C. P. Green, H. M. Halläander, and P. Maghoul, Fully coupled hydro-mechanical–chemical continuum modeling of fluid percolation through rock salt, International Journal of Rock Mechanics and Mining Sciences, 186, 2024. https://doi.org/10.1016/j.ijrmms.2024.105985 [Download] [View Abstract]In domal and bedded rock salt geothermal reservoirs, geochemical dissolution of the in-situ rock salt formation can alter fluid transport properties, thus impacting fluid flow. Coupled Hydro-mechanical–chemical (HMC) modeling is a useful tool to evaluate fluid transport through rock salt geothermal systems and to assess their economic potential. Existing continuum-based numerical simulation of fluid transport through rock salt relies on the polyhedral orientation of rock salt crystal boundaries as potential fluid pathways, employing a deformation-dependent permeability model to depict pressure-driven fluid flow through rock salt. However, this numerical approach is exclusively HM-coupled and overlooks the influence of halite dissolution/precipitation on the permeability model. This study extends the deformation-dependent permeability model to account for halite dissolution by adopting a reverse mineral growth approach. Using this extended (HMC-coupled) model, we capture the relevance of geochemical reactions on the response of rock salt formations undergoing pressure-driven fluid percolation. The resulting simulations predict a lower fluid pressure than the HM-coupled scenario, highlighting the impact of halite dissolution on fluid flow through rock salt.
53.
Wei, Z., L. Jiang, L. Tao, S. Chen, Z. Dong, Y. Chen, B. Liu, D. Xue, X.-Z. Kong, J. Zhang, and Z. Chen, Towards A Hydrogen Economy: Understanding Pore Alterations in Underground Coal Gasification, Journal of Cleaner Production, (in press). https://doi.org/10.1016/j.jclepro.2024.144325 [Download] [View Abstract]Underground coal gasification (UCG) is gaining significant attention worldwide as a promising clean energy solution, particularly in conjunction with hydrogen production, amidst the global shift towards a hydrogen-based economy. However, existing research on hydrogen-oriented underground coal gasification (HUCG) has primarily emphasized hydrogen generation and syngas production optimization, neglecting a comprehensive analysis of pore space and permeability changes surrounding the cavities during water injection. To address this gap, we conducted a study to elucidate the alterations in pore structure of the surrounding coal seam during cavity development within the HUCG framework. Utilizing a large-scale 3D UCG model with a water injection well, we examined key parameters including temperature, porosity, permeability, and water saturation at various grid points around the cavity. Our modeling outcomes reveal that water injection influences both the cavity's development trajectory and coal pore characteristics, indicating a strong interplay between hydrological and physiochemical processes in UCG. Additionally, analysis of water saturation curves validates sensible injection rates for feasible HUCG implementation. This work provides important insights into the changes in coal morphology during hydrogen-oriented underground coal gasification, offers theoretical support for scaling up hydrogen production and advancing the development of a hydrogen-centric clean energy system. It contributes to the global shift towards a more diversified and sustainable hydrogen-based energy framework, accelerating political decision-making and technological progress.
52.
Zhang, N., L. Zhao, L. Jiang, Y. Ju, Z. Luo, P. Liu, Y. Pei, K. Wen, et. et., X.-Z. Kong, and et. et., Innovative temperature-sensitive phase-transition fracturing: Boosting unconventional resource development, The Innovation Energy, 1, pp. 100039-100040, 2024. https://doi.org/10.59717/j.xinn-energy.2024.100039 [Download] [View Abstract]China's energy structure is primarily based on coal, oil, and natural gas, with a recent rise in the use of natural gas and renewable energy. Oil accounts for approximately 17.9% of energy consumption, while natural gas makes up about 8.4%. Although shale oil, gas, and other unconventional resources constitute a minor part of China's energy mix, their development is crucial. Exploiting these resources can reduce dependence on imported oil and gas, enhance energy supply diversity and stability. This strategy will not only secure energy but also promote sustainable economic development and environmental improvements.
51.
Li, Y., G. Peng, T. Du, L. Jiang, and X.-Z. Kong, Advancing Fractured Geothermal System Modelling with Artificial Neural Network and Bidirectional Gated Recurrent Unit, Applied Energy, 372, 2024. https://doi.org/10.1016/j.apenergy.2024.123826 [Download] [View Abstract]Geothermal energy plays a pivotal role in the global energy transition towards carbon-neutrality, providing a sustainable, renewable, and abundant source of clean energy in the fight against climate change. Despite advancements, the optimal engineering of geothermal systems and energy extraction remains challenging, particularly in accurately predicting production temperatures. Here, we present an innovative numerical approach using a hybrid neural network that merges Artificial Neural Network (ANN) and Bidirectional Gated Recurrent Unit (BiGRU). With this hybrid network, we comprehensively assess 22 influential factors, including construction parameters, physical parameters, and well layout, which influence thermal breakthrough time and production temperature across varying fracture density. While the ANN captures the nonlinear interplay between static constraints and thermal breakthrough time, the BiGRU adeptly handles the temporal intricacies of production temperature. We examine the impact of ANN parameters on model performance, in comparison with conventional temporal models like Recurrent Neural Network (RNN), Long Short-Term Memory (LSTM), Gate Recurrent Unit (GRU), and BiGRU. Our findings reveal that augmenting hidden layers and neurons in ANN enhances its capacity to model intricate nonlinear processes, albeit with a risk of overfitting. Notably, the relu activation function emerges as optimal for managing nonlinear processes, while BiGRU excels over RNN, GRU, and LSTM models in forecasting production temperature of fractured geothermal systems, owing to its ability to extract implicit information from time series across historical and future trajectories. Crucially, the prediction uncertainty, measured by Root Mean Square Error (RMSE) and Mean Absolute Error (MAE), remains within 0.15, underscoring the precision and efficacy of our hybrid approach in forecasting geothermal energy extraction. This study presents a significant stride towards a high-precision and efficient predictive framework crucial for advancing geothermal energy extraction in the broader context of renewable energy transition endeavors.
50.
Wang, N., X.-Z. Kong, and D. Zhang, Physics-Informed Convolutional Decoder (PICD): A novel approach for direct inversion of heterogeneous subsurface flow, Geophysical Research Letter, 2024. https://doi.org/10.1029/2024GL108163 [Download] [View Abstract]We propose a physics-informed convolutional decoder (PICD) framework for inverse modeling of heterogenous groundwater flow. PICD stands out as a direct inversion method, eliminating the need for repeated forward model simulations. The framework combines data-driven and physics-driven approaches by integrating monitoring data and domain knowledge into the inversion process. PICD utilizes a convolutional decoder to effectively approximate the spatial distribution of hydraulic heads, while Karhunen–Loeve expansion (KLE) is employed to parameterize hydraulic conductivities. During the training process, the stochastic vector in KLE and the parameters of the convolutional decoder are adjusted simultaneously to minimize the data-mismatch and the physical violation. The final optimized stochastic vectors correspond to the estimation of hydraulic conductivities, and the trained convolutional decoder can predict the evolution and distribution of hydraulic heads. Various scenarios of groundwater flow are examined and results demonstrate the framework's capability to accurately estimate heterogeneous hydraulic conductivities and to deliver satisfactory predictions of hydraulic heads, even with sparse measurements.
49.
Sookhak Lari, K., G. Davis, A. Kumar, J. Rayner, X.-Z. Kong, and M.O. Saar, The Dynamics of Per- and Polyfluoroalkyl Substances (PFAS) at Interfaces in Porous Media: A Computational Roadmap from Nanoscale Molecular Dynamics Simulation to Macroscale Modeling, ACS Omega, 2024. https://doi.org/10.1021/acsomega.3c09201 [Download] [View Abstract]Managing and remediating perfluoroalkyl and polyfluoroalkyl substance (PFAS) contaminated sites remains challenging. The major reasons are the complexity of geological media, partly unknown dynamics of the PFAS in different phases and at fluid− fluid and fluid−solid interfaces, and the presence of cocontaminants such as nonaqueous phase liquids (NAPLs). Critical knowledge gaps exist in understanding the behavior and fate of PFAS in vadose and saturated zones and in other porous media such as concrete and asphalt. The complexity of PFAS−surface interactions warrants the use of advanced characterization and computational tools to understand and quantify nanoscale behavior of the molecules. This can then be upscaled to the microscale to develop a constitutive relationship, in particular to distinguish between surface and bulk diffusion. The dominance of surface diffusion compared to bulk diffusion results in the solutocapillary Marangoni effect, which has not been considered while investigating the fate of PFAS. Without a deep understanding of these phenomena, derivation of constitutive relationships is challenging. The current Darcy scale mass-transfer models use constitutive relationships derived from either experiments or field measurements, which makes their applicability potentially limited. Here we review current efforts and propose a roadmap for developing Darcy scale transport equations for PFAS. We find that this needs to be based on systematic upscaling of both experimental and computational studies from nano- to microscales. We highlight recent efforts to undertake molecular dynamics simulations on problems with similar levels of complexity and explore the feasibility of conducting nanoscale simulations on PFAS dynamics at the interface of fluid pairs.
48.
Wang, N., H. Chang, X.-Z. Kong, and D. Zhang, Deep learning based closed-loop well control optimization of geothermal reservoir with uncertain permeability, Renewable Energy, 211, pp. 379-394, 2023. https://doi.org/10.1016/j.renene.2023.04.088 [Download] [View Abstract]To maximize the economic benefits of geothermal energy production, it is essential to optimize geothermal reservoir management strategies, in which geologic uncertainty should be considered. In this work, we propose a closed-loop optimization framework, based on deep learning surrogates, for the well control optimization of geothermal reservoirs. In this framework, we construct a hybrid convolution–recurrent neural network surrogate, which combines the convolution neural network (CNN) and long short-term memory (LSTM) recurrent network. The convolution structure can extract spatial information of reservoir property fields and the recurrent structure can approximate sequence-to-sequence mapping. The trained model can predict time-varying production responses (rate, temperature, etc.) for cases with different permeability fields and well control sequences. In this closed-loop optimization framework, production optimization, based on the differential evolution (DE) algorithm, and data assimilation, based on the iterative ensemble smoother (IES), are performed alternately to achieve a real-time well control optimization and to estimate reservoir properties (e.g. permeability) as the production proceeds. In addition, the averaged objective function over the ensemble of geologic parameter estimates is adopted to consider geologic uncertainty in the optimization process. Geothermal reservoir production cases are examined to evaluate the performance of the proposed closed-loop optimization framework. Our results show that the proposed framework can achieve efficient and effective real-time optimization and data assimilation in the geothermal reservoir production process.
47.
Kong, X.-Z., M. Ahkami, I. Naets, and M.O. Saar, The role of high-permeability inclusion on solute transport in a 3D-printed fractured porous medium: An LIF-PIV integrated study, Transport in Porous Media, 2023. https://doi.org/10.1007/s11242-022-01827-y [Download] [View Abstract]It is well-known that the presence of geometry heterogeneity in porous media enhances solute mass mixing due to fluid velocity heterogeneity. However, laboratory measurements are still sparse on characterization of the role of high-permeability inclusions on solute transport, in particularly concerning fractured porous media. In this study, the transport of solutes is quantified after a pulse-like injection of soluble fluorescent dye into a 3D-printed fractured porous medium with distinct high-permeability (H-k) inclusions. The solute concentration and the pore-scale fluid velocity are determined using laser-induced fluorescence and particle image velocimetry techniques. The migration of solute is delineated with its breakthrough curve (BC), temporal and spatial moments, and mixing metrics (including the scalar dissipation rate, the volumetric dilution index, and the flux-related dilution index) in different regions of the medium. With the same H-k inclusions, compared to a H-k matrix, the low-permeability (L-k) matrix displays a higher peak in its BC, less solute mass retention, a higher peak solute velocity, a smaller peak dispersion coefficient, a lower mixing rate, and a smaller pore volume being occupied by the solute. The flux-related dilution index clearly captures the striated solute plume tails following the streamlines along dead-end fractures and along the interface between the H-k and L-k matrices. We propose a normalization of the scalar dissipation rate and the volumetric dilution index with respect to the maximum regional total solute mass, which offers a generalized examination of solute mixing for an open region with a varying total solute mass. Our study presents insights into the interplay between the geometric features of the fractured porous medium and the solute transport behaviors at the pore scale.
46.
Wang, X., X.-Z. Kong, L. Hu, and Z. Xu, Mapping conduits in two-dimensional heterogeneous karst aquifers using hydraulic tomography, Journal of Hydrology, 617, 2023. https://doi.org/10.1016/j.jhydrol.2022.129018 [Download] [View Abstract]Hydraulic tomography (HT) is a well-established approach to yield the spatial distribution of hydraulic conductivity of an aquifer. This work explores the potential of HT for the characterization of the distribution and connectivity of conduits in a two-dimensional sandbox and its corresponding synthetic aquifer. Two inversion techniques were implemented and compared: the geostatistics-based inversion which uses the simultaneous successive linear estimator (SimSLE) algorithm to conduct stochastic inversions on the transient hydraulic heads, and the travel time-based inversion which employs the simultaneous iterative reconstruction technique (SIRT) algorithm on the hydraulic travel times for tomography reconstructions. Four artificial karst conduits of different geometries were placed in an aquifer of layer with different hydraulic conductivities. We conducted 6 pumping tests at 6 different locations, and the resultant pressure responses were recorded at 42 observation points in both the sandbox and the corresponding synthetic aquifer. The measured data were then used for the inversion of hydraulic diffusivity using the SimSLE and SIRT algorithms. Our results show that both algorithms were able to approximately identify the embedded karst conduits and yield similar hydraulic diffusivity distribution. Statistically, the travel time-based inversion re-constructed high-contrast diffusivities which clearly differentiate the karst structures from the surrounding matrix. The geostatistics-based SimSLE algorithm yields a better agreement on the positions and the shapes of the embedded karst structures, compared to those obtained by the travel time-based SIRT algorithm. Uncertainties and limitations of our results are also discussed in this work, followed by recommendations on hydraulic tests in karst aquifers.
45.
Li, Z., X. Ma, X.-Z. Kong, M.O. Saar, and D. Vogler, Permeability evolution during pressure-controlled shear slip in saw-cut and natural granite fractures, Rock Mechanics Bulletin, 2023. https://doi.org/10.1016/j.rockmb.2022.100027 [Download] [View Abstract]Fluid injection into rock masses is involved during various subsurface engineering applications. However, elevated fluid pressure, induced by injection, can trigger shear slip(s) of pre-existing natural fractures, resulting in changes of the rock mass permeability and thus injectivity. However, the mechanism of slip-induced permeability variation, particularly when subjected to multiple slips, is still not fully understood. In this study, we performed laboratory experiments to investigate the fracture permeability evolution induced by shear slip in both saw-cut and natural fractures with rough surfaces. Our experiments show that compared to saw-cut fractures, natural fractures show much small effective stress when the slips induced by triggering fluid pressures, likely due to the much rougher surface of the natural fractures. For natural fractures, we observed that a critical shear displacement value in the relationship between permeability and accumulative shear displacement: the permeability of natural fractures initially increases, followed by a permeability decrease after the accumulative shear displacement reaches a critical shear displacement value. For the saw-cut fractures, there is no consistent change in the measured permeability versus the accumulative shear displacement, but the first slip event often induces the largest shear displacement and associated permeability changes. The produced gouge material suggests that rock surface damage occurs during multiple slips, although, unfortunately, our experiments did not allow quantitatively continuous monitoring of fracture surface property changes. Thus, we attribute the slip-induced permeability evolution to the interplay between permeability reductions, due to damages of fracture asperities, and permeability enhancements, caused by shear dilation, depending on the scale of the shear displacement.
44.
Naets, I., M. Ahkami, P.-W. Huang, M. O. Saar, and X.-Z. Kong, Shear induced fluid flow path evolution in rough-wall fractures: A particle image velocimetry examination, Journal of Hydrology, 610/127793, 2022. https://doi.org/10.1016/j.jhydrol.2022.127793 [Download] [View Abstract]Rough-walled fractures in rock masses, as preferential pathways, largely influence fluid flow, solute and energy transport. Previous studies indicate that fracture aperture fields could be significantly modified due to shear displacement along fractures. We report experimental observations and quantitative analyses of flow path evolution within a single fracture, induced by shear displacement. Particle image velocimetry and refractive index matching techniques were utilized to determine fluid velocity fields inside a transparent 3D-printed shear-able rough fracture. Our analysis indicate that aperture variability and correlation length increase with the increasing shear displacement, and they are the two key parameters, which govern the increases in velocity variability, velocity longitudinal correlation length, streamline tortuosity, and variability of streamline spacing. The increase in aperture heterogeneity significantly impacts fluid flow behaviors, whilst changes in aperture correlation length further refine these impacts. To our best knowledge, our study is the first direct measurements of fluid velocity fields and provides insights into the impact of fracture shear on flow behavior.
43.
Lima, M., H. Javanmard, D. Vogler, M.O. Saar, and X.-Z. Kong, Flow-through Drying during CO2 Injection into Brine-filled Natural Fractures: A Tale of Effective Normal Stress, International Journal of Greenhouse Gas Control, 109, pp. 103378, 2021. https://doi.org/10.1016/j.ijggc.2021.103378 [Download] [View Abstract]Injecting supercritical CO2 (scCO2) into brine-filled fracture-dominated reservoirs causes brine displacement and possibly evaporite precipitations that alter the fracture space.
Here, we report on isothermal near-field experiments on scCO2-induced flow-through drying in a naturally fractured granodiorite specimen under effective normal stresses of 5-10 MPa, where two drying regimes are identified. A novel approach is developed to delineate the evolution of brine saturation and relative permeability from fluid production and differential pressure measurements. Under higher compressive stresses, the derived relative permeability curves indicate lower mobility of brine and higher mobility of the scCO2 phase. The derived fractional flow curves also suggest an increase in channelling and a decrease in brine displacement efficiencies under higher compressive stresses. Finally, lowering compressive stresses seems to hinder water evaporation. Our experimental results assist in understanding the behaviour of the injectivity of fractures and fracture networks during subsurface applications that involve scCO2 injection into saline formations.
42.
Ma, J., M. Ahkami, M.O. Saar, and X.-Z. Kong, Quantification of mineral accessible surface area and flow-dependent fluid-mineral reactivity at the pore scale, Chemical Geology, 563, pp. 120042, 2021. https://doi.org/10.1016/j.chemgeo.2020.120042 [Download] [View Abstract]Accessible surface areas (ASAs) of individual rock-forming minerals exert a fundamental control on the maximum mineral reactivity with formation fluids. Notably, ASA efficiency during fluid-rock reactions can vary by orders of magnitude, depending on the inflow fluid chemistry and the velocity field. Due to the lack of adequate quantification methods, determining the mineral-specific ASAs and their reaction efficiency still remain extremely difficult. Here, we first present a novel joint method that appropriately calculates ASAs of individual minerals in a multi-mineral sandstone. This joint method combines SEM-image processing results and Brunauer-Emmett-Teller (BET) surface area measurements by a Monte-Carlo algorithm to derive scaling factors and ASAs for individual minerals at the resolution of BET measurements. Using these atomic-scale ASAs, we then investigate the impact of flow rate on the ASA efficiency in mineral dissolution reactions during the injection of CO2-enriched brine. This is done by conducting a series of pore-scale reactive transport simulations, using a two-dimensional (2D) scanning electron microscopy (SEM) image of this sandstone. The ASA efficiency is determined employing a domain-averaged dissolution rate and the effective surface area of the most reactive phase in the sandstone (dolomite). As expected, the dolomite reactivity is found to increase with the flow rate, due to the on average high fluid reactivity. The surface efficiency increases slightly with the fluid flow rate, and reaches a relatively stable value of about 1%. The domain averaged method is then compared with the in-out averaged method (i.e the “Black-box” approach), which is often used to analyzed the experimental observations. The in-out averaged method yields a considerable overestimation of the fluid reactivity, a small underestimation of the dolomite reactivity, and a considerable underestimation of the ASA efficiency. The discrepancy between the two methods is becoming smaller when the injection rate increases. Our comparison suggests that the result interpretation of the in-out averaged method should be contemplated, in particular, when the flow rate is small. Nonetheless, our proposed ASA determination method should facilitate accurate calculations of fluid-mineral reactivity in large-scale reactive transport simulations, and we advise that an upscaling of the ASA efficiency needs to be carefully considered, due to the low surface efficiency.
41.
Ma, Y., X.-Z. Kong, C. Zhang, A. Scheuermann, D. Bringemeier, and L. Li, Quantification of natural CO2 emission through faults and fracture zones in coal basins, Geophysical Research Letters, 48, pp. e2021GL092693, 2021. https://doi.org/10.1029/2021GL092693 [Download] [View Abstract]With the presence of highly permeable pathways, such as faults and fractures zones, coal seam gases, particularly CO2, could potentially migrate upwardly from the coal deposits into the shallow subsurface and then to the atmosphere. This letter reports soil gas mapping and gamma ray survey in coal basin of Hunter River Valley, Australia. The survey facilitated the delineation of fault structures across the sampling regions, where the identified faults were confirmed by an independent drilling investigation later. Furthermore, to evaluate the gas emission fluxes from coalbeds through fault zones, the measured CO2 concentrations, coupled with an inverse modelling, enable the estimation of the width of the fault zone and associated CO2 emission flux in the range of 2×10\(^{-5}\)-6×10\(^{-5}\) mol/m\(^{2}\)/s at the study site. Our new approach provides a way to determine emissions of gases from deep formations, which may contribute considerably to the greenhouse gases cycles.
40.
Lima, M., P. Schädle, C. Green, D. Vogler, M.O. Saar, and X.-Z. Kong, Permeability Impairment and Salt Precipitation Patterns during CO2 Injection into Single Natural Brine-filled Fractures, Water Resources Research, 56/8, pp. e2020WR027213, 2020. https://doi.org/10.1029/2020WR027213 [Download] [View Abstract]Formation dry-out in fracture-dominated geological reservoirs may alter the fracture space, impair rock absolute permeability and cause a significant decrease in well injectivity. In this study, we numerically model the dry-out processes occurring during supercritical CO2 (scCO2) injection into single brine-filled fractures and evaluate the potential for salt precipitation under increasing effective normal stresses in the evaporative regime. We use an open-source, parallel finite-element framework to numerically model two-phase flow through 2-Dimensional fracture planes with aperture fields taken from naturally fractured granite cores at the Grimsel Test Site in Switzerland. Our results reveal a displacement front and a subsequent dry-out front in all simulated scenarios, where higher effective stresses caused more flow channeling, higher rates of water evaporation and larger volumes of salt precipitates. However, despite the larger salt volumes, the permeability impairment was lower at higher effective normal stresses. We conclude that the spatial distribution of the salt, precipitated in fractures with heterogeneous aperture fields, strongly affects the absolute permeability impairment caused by formation dry-out. The numerical simulations assist in understanding the behavior of the injectivity in fractures and fracture networks during subsurface applications that involve scCO2 injection into brine.
39.
Ma, J., L. Querci, B. Hattendorf, M.O. Saar, and X.-Z. Kong, The effect of mineral dissolution on the effective stress law for permeability in a tight sandstone, Geophysical Research Letters, 2020. https://doi.org/10.1029/2020GL088346 [Download] [View Abstract]We present flow-through experiments to delineate the processes involved in permeability changes driven by effective stress variations and mineral cement dissolution in porous rocks. CO2-enriched brine is injected continuously into a tight sandstone under in-situ reservoir conditions for 455 hours. Due to the dolomite cement dissolution, the bulk permeability of the sandstone specimen significantly increases, and two dissolution passages are identified near the fluid inlet by X-ray CT imaging. Pre- and post-reaction examinations of the effective stress law for permeability suggest that after reaction the bulk permeability is more sensitive to pore pressure changes and less sensitive to effective stress changes. These observations are corroborated by Scanning Electron Microscopy and X-ray CT observations. This study deepens our understanding of the effect of mineral dissolution on the effective stress law for permeability, with implications for characterizing subsurface mass and energy transport, particularly during fluid injection/production into/from geologic reservoirs.
38.
Tutolo, B., A. Luhmann, X.-Z. Kong, B. Bagley, D. Alba-Venero, N. Mitchell, M.O. Saar, and W.E. Seyfried, Contributions of visible and invisible pores to reactive transport in dolomite, Geochemical Perspectives Letters, I4, pp. 42-46, 2020. https://doi.org/10.7185/geochemlet.2022 [Download] [View Abstract]Recent technical advances have demonstrated the importance of pore-scale geochemical processes for governing Earth's evolution. However, the contribution of pores at different scales to overall geochemical reactions remains poorly understood. Here, we integrate multiscale characterization and reactive transport modeling to study the contribution of pore-scale geochemical proceses to the hydrogeochemical evolution of dolomite rock samples during CO2-driven dissolution experiments. Our results demonstrate that approximately half of the total pore volume is invisible at the scale of commonly used imaging techniques. Comparison of pre- and post-experiment analyses demonstrate that porosity-increasing, CO2-driven dissolution processes preferentially occur in pores 600 nm – 5 μm in size, but pores <600 nm in size show no change during experimental alteration. This latter observation, combined with the anomalously high rates of trace element release during the experiments, suggests that nanoscale pores are accessible to through-flowing fluids. A three-dimensional simulation performed directly on one of the samples shows that steady-state pore-scale trace element reaction rates must be ~10× faster than that of dolomite in order to match measured effluent concentrations, consistent with the large surface area-to-volume ratio in these pores. Together, these results yield a new conceptual model of pore-scale processes, and urge caution when interpreting the trace element concentrations of ancient carbonate rocks.
37.
Kittilä, A., M.R. Jalali, M.O. Saar, and X.-Z. Kong, Solute tracer test quantification of the effects of hot water injection into hydraulically stimulated crystalline rock, Geothermal Energy, 8/17, 2020. https://doi.org/10.1186/s40517-020-00172-x [Download] [View Abstract]When water is injected into a fracture-dominated reservoir that is cooler or hotter than the injected water, the reservoir permeability is expected to be altered by the injection-induced thermo-mechanical effects, resulting in the redistribution of fluid flow in the reservoir. These effects are important to be taken into account when evaluating the performance and lifetime particularly of Enhanced Geothermal Systems (EGS). In this paper, we compare the results from two dye tracer tests, conducted before (at ambient temperature of 13 °C) and during the injection of 45 °C hot water into a fractured crystalline rock at the Grimsel Test Site in Switzerland. Conducting a moment analysis on the recovered tracer residence time distribution (RTD) curves, we observe, after hot water injection, a significant decrease in the total tracer recovery. This recovery decrease strongly suggests that fluid flow was redistributed in the studied rock volume and that the majority of the injected water was lost to the far-field. Furthermore, by using temperature measurements, obtained from the same locations as the tracer RTD curves, we conceptualize an approach to estimate the fracture surface area contributing to the heat exchange between the host rock and the circulating fluid. Our moment analysis and simplified estimation of fracture surface area provide insights into the hydraulic properties of the hydraulically active fracture system and the changes in fluid flow. Such insights are important to assess the heat exchange performance of a geothermal formation during fluid circulation and to estimate the lifetime of the geothermal formation, particularly in EGS.
36.
Jia, Y., W. Wu, and X.-Z. Kong, Injection-induced slip heterogeneity on faults in shale reservoirs, International Journal of Rock Mechanics and Mining Sciences, 131, pp. 1-6, 2020. https://doi.org/10.1016/j.ijrmms.2020.104363 [Download] [View Abstract]Managing fluid stimulation protocols is an effective means to mitigate the risk of injection-induced earthquakes during shale gas development. The success of these protocols is dependent on our understanding of fluid pressure heterogeneity and the associated inhomogeneous slip on critically stressed faults. Here we show the evolution of velocity-weakening zone on a simulated fault, derived from fluid injection and velocity stepped experiments, and the corresponding non-uniform fluid pressure distribution, recovered from coupled hydro-mechanical simulations. Our results indicate that the sharp extension of velocity-weakening zone occurs before the nucleation of fault rupture, which could be an indicator to avoid the reactivation of other fault patches beyond the stimulated zone. The dynamic rupture is estimated to extend much faster than the maximum speed of the velocity-weakening zone front. We infer that the velocity-weakening zone may further expand and fully control the fault behavior after multiple slip events.
35.
Kittilä, A., M.R. Jalali, M. Somogyvári, K.F. Evans, M.O. Saar, and X.-Z. Kong, Characterization of the effects of hydraulic stimulation with tracer-based temporal moment analysis and tomographic inversion, Geothermics, 86/101820, 2020. https://doi.org/10.1016/j.geothermics.2020.101820 [Download] [View Abstract]Tracer tests were conducted as part of decameter-scale in-situ hydraulic stimulation experiments at the Grimsel Test Site to investigate the hydraulic properties of a stimulated crystalline rock volume and to study the stimulation-induced hydrodynamic changes. Temporal moment analysis yielded an increase in tracer swept pore volume with prominent flow channeling. Post-stimulation tomographic inversion of the hydraulic conductivity, K, distribution indicated an increase in the geometric mean of logK and a decrease in the Dykstra-Parsons heterogeneity index. These results indicate that new flow path connections were created by the stimulation programs, enabling the tracers to sweep larger volumes, while accessing flow paths with larger hydraulic conductivities.
34.
Ahkami, M., A. Parmigiani, P.R. Di Palma, M.O. Saar, and X.-Z. Kong, A lattice-Boltzmann study of permeability-porosity relationships and mineral precipitation patterns in fractured porous media, Computational Geosciences, 2020. https://doi.org/10.1007/s10596-019-09926-4 [Download] [View Abstract]Mineral precipitation can drastically alter a reservoir’s ability to transmit mass and energy during various engineering/natural subsurface processes, such as geothermal energy extraction and geological carbon dioxide sequestration. However, it is still challenging to explain the relationships among permeability, porosity, and precipitation patterns in reservoirs, particularly in fracture-dominated reservoirs. Here, we investigate the pore-scale behavior of single-species mineral precipitation reactions in a fractured porous medium, using a phase field lattice-Boltzmann method. Parallel to the main flow direction, the medium is divided into two halves, one with a low-permeability matrix and one with a high-permeability matrix. Each matrix contains one flow-through and one dead-end fracture. A wide range of species diffusivity and reaction rates is explored to cover regimes from advection- to diffusion-dominated, and from transport- to reaction-limited. By employing the ratio of the Damköhler (Da) and the Peclet (Pe) number, four distinct precipitation patterns can be identified, namely (1) no precipitation (Da/Pe < 1), (2) near-inlet clogging (Da/Pe > 100), (3) fracture isolation (1 < Da/Pe < 100 and Pe > 1), and (4) diffusive precipitation (1 < Da/Pe < 100 and Pe < 0.1). Using moment analyses, we discuss in detail the development of the species (i.e., reactant) concentration and mineral precipitation fields for various species transport regimes. Finally, we establish a general relationship among mineral precipitation pattern, porosity, and permeability. Our study provides insights into the feedback loop of fluid flow, species transport, mineral precipitation, pore space geometry changes, and permeability in fractured porous media.
33.
Ahkami, M., T. Roesgen, M.O. Saar, and X.-Z. Kong, High-resolution temporo-ensemble PIV to resolve pore-scale flow in 3D-printed fractured porous media, Transport in Porous Media, 129/2, pp. 467-483, 2019. https://doi.org/10.1007/s11242-018-1174-3 [Download] [View Abstract]Fractures are conduits that can enable fast advective transfer of (fluid, solute, reactant, particle, etc.) mass and energy. Such fast transfer can significantly affect pore-scale physico-chemical processes, which can in turn affect macroscopic mass and energy transport characteristics. Here, flooding experiments are conducted in a well-characterized fractured porous medium, manufactured by 3D printing. Given steady-state flow conditions, the micro-structure of the two-dimensional (2D) pore fluid flow field is delineated to resolve fluid velocities on the order of a sub-millimeter per second. We demonstrate the capabilities of a new temporo-ensemble Particle Image Velocimetry (PIV) method by maximizing its spatial resolution, employing in-line illumination. This method is advantageous as it is capable of minimizing the number of pixels, required for velocity determinations, down to one pixel, thereby enabling resolving high spatial resolutions of velocity vectors in a large field of view (FOV). While the main goal of this study is to introduce a novel experimental and velocimetry framework, this new method is then applied to specifically improve the understanding of fluid flow through fractured porous media. Histograms of measured velocities indicate log-normal and Gaussian-type distributions of longitudinal and lateral velocities in fractures, respectively. The magnitudes of fluid velocities in fractures and the flow interactions between fractures and matrices are shown to be influenced by the permeability of the background matrix and the orientation of the fractures.
32.
Parmigiani, A., P.R. Di Palma, S. Leclaire, F. Habib, and X.-Z. Kong, Characterization of transport-enhanced phase separation in porous media using a lattice-Boltzmann method, Geofluids, 2019, 2019. https://doi.org/10.1155/2019/5176410 [Download] [View Abstract]Phase separation of formation fluids in subsurface introduces hydrodynamic perturbations which are critical for mass and energy transport of geofluids. Here, we present pore-scale lattice-Boltzmann simulations to investigate the hydrodynamical response of a porous-system to the emergence of non-wetting droplets under background hydraulic gradients. A wide parameter space of capillary number and fluid saturation is explored to characterize the droplet evolution, the droplet size and shape distribution, and the capillary-clogging patterns. We find that clogging is favored by high capillary stress; nonetheless clogging occurs at high non-wetting saturation (larger than 0.3), denoting the importance of convective transport on droplet-growth and permeability. Moreover, droplets are more sheared at low capillary number, however solid matrix plays a key role on droplet's volume-to-surface ratio.
31.
Romano, E., J. Jimenez-Martinez, A. Parmigiani, X.-Z. Kong, and I. Battiato, Contribution of Pore-Scale Approach to Macroscale Geofluids Modelling in Porous Media, Geofluids, 2019, 2019. https://doi.org/10.1155/2019/6305391 [Download] [View Abstract]Understanding the fundamental mechanisms of fluid flows and reactive transport in natural systems is a major challenge for several fields of Earth sciences (e.g. hydrology, soil science, volcanology) and Geo/Environmental-engineering (CO2 sequestration, NAPLS contamination, geothermal energy, oil&gas reservoir exploitation).
The hierarchical structures of natural system (e.g. heterogeneity of geological formations) as well as the different behaviour of single and multi-phase fluids at the pore-scale coupled with the nonlinearity of underlying reactive processes necessitate investigating these aspects at the scale at which they physically occur, the scale of pore and fractures.
Recent improvements in pore-scale computational modelling, together with the development of non- invasive microscopic imaging technology and the latest microfluidics technics are allowing the vast field of porous & fractured media research to benefit of major advances due to: 1) an improved understanding and description of pore-scale mechanisms and 2) the ability of thinking in terms of coupled processes.
The contributions collected in this Special Issue, although far from constituting a comprehensive picture of the “pore-scale world”, however offer a good example of the potentialities of such an approach to investigate a wide range of processes usually observed at macro-scale, but whose underlying physical and chemical processes take place at micro-scale.
30.
Ma, J., L. Querci, B. Hattendorf, M.O. Saar, and X.-Z. Kong, Toward a Spatiotemporal Understanding of Dolomite Dissolution in Sandstone by CO2‑Enriched Brine Circulation, Environmental Science & Technology, 2019. https://doi.org/10.1021/acs.est.9b04441 [Download] [View Abstract]In this study, we introduce a stochastic method to delineate the mineral effective surface area (ESA) evolution during a re-cycling reactive flow-through transport experiment on a sandstone under geologic reservoir conditions, with a focus on the dissolution of its dolomite cement, Ca$_{1.05}$Mg$_{0.75}$Fe$_{0.2}$(CO$_3$)$_2$. CO$_2$-enriched brine was circulated through this sandstone specimen for 137 cycles ($\sim$270 hours) to examine the evolution of in-situ hydraulic properties and CO$_2$-enriched brine-dolomite geochemical reactions. The bulk permeability of the sandstone specimen decreased from 356 mD before the reaction to 139 mD after the reaction, while porosity increased from 21.9\% to 23.2\% due to a solid volume loss of 0.25 ml. Chemical analyses on experimental effluents during the first cycle yielded a dolomite reactivity of $\sim$2.45 mmol~m$^{-3}$~s$^{-1}$, a corresponding sample-averaged ESA of $\sim$8.86$\times 10^{-4}$~m$^2$/g, and an ESA coefficient of 1.36$\times 10^{-2}$, indicating limited participation of the physically exposed mineral surface area. As the dissolution reaction progressed, the ESA is observed to first increase, then decrease. This change in ESA can be qualitatively reproduced employing SEM-image-based stochastic analyses on dolomite dissolution. These results provide a new approach to analyze and upscale the ESA during geochemical reactions, which are involved in a wide range of geo-engineering operations.
29.
Lima, M.M., D. Vogler, L. Querci, C. Madonna, B. Hattendorf, M.O. Saar, and X.-Z. Kong, Thermally driven fracture aperture variation in naturally fractured granites, Geothermal Energy Journal, 7/1, pp. 1-23, 2019. https://doi.org/10.1186/s40517-019-0140-9 [Download] [View Abstract]Temperature variations often trigger coupled thermal, hydrological, mechanical, and chemical (THMC) processes that can significantly alter the permeability/impedance of fracture-dominated deep geological reservoirs. It is thus necessary to quantitatively explore the associated phenomena during fracture opening and closure as a result of temperature change. In this work, we report near-field experimental results of the effect of temperature on the hydraulic properties of natural fractures under stressed conditions (effective normal stresses of 5-25 MPa). Two specimens of naturally fractured granodiorite cores from the Grimsel Test Site in Switzerland were subjected to flow-through experiments with a temperature variation of 25-140 °C to characterize the evolution of fracture aperture/permeability. The fracture surfaces of the studied specimens were morphologically characterized using photogrammetry scanning. Periodic measurements of the efflux of dissolved minerals yield the net removal mass, which is correlated to the observed rates of fracture closure. Changes measured in hydraulic aperture are significant, exhibiting reductions of 20-75 % over the heating/cooling cycles. Under higher confining stresses, the effects in fracture permeability are irreversible and notably time-dependent. Thermally driven fracture aperture variation was more pronounced in the specimen with the largest mean aperture width and spatial correlation length. Gradual fracture compaction is likely controlled by thermal dilation, mechanical grinding, and pressure dissolution due to increased thermal stresses exerted over the contacting asperities, as confirmed by the analyses of hydraulic properties and efflux mass.
28.
Kittilä, A., M.R. Jalali, K.F. Evans, M. Willmann, M.O. Saar, and X.-Z. Kong, Field Comparison of DNA-Labeled Nanoparticle and Solute Tracer Transport in a Fractured Crystalline Rock, Water Resources Research, 2019. https://doi.org/10.1029/2019WR025021 [Download]
27.
Kong, X.-Z., C. Deuber, A. Kittilä, M. Somogyvari, G. Mikutis, P. Bayer, W.J. Stark, and M.O. Saar, Tomographic reservoir imaging with DNA-labeled silica nanotracers: The first field validation, Environmental Science &Technology, 52/23, pp. 13681-13689, 2018. https://doi.org/10.1021/acs.est.8b04367 [Download] [View Abstract]This study presents the first field validation of using DNA-labeled silica
nanoparticles as tracers to image subsurface reservoirs by travel time based tomography. During
a field campaign in Switzerland, we performed short-pulse tracer tests under a forced hydraulic
head gradient to conduct a multisource−multireceiver tracer test and tomographic inversion,
determining the two-dimensional hydraulic conductivity field between two vertical wells.
Together with three traditional solute dye tracers, we injected spherical silica nanotracers,
encoded with synthetic DNA molecules, which are protected by a silica layer against damage due
to chemicals, microorganisms, and enzymes. Temporal moment analyses of the recorded tracer
concentration breakthrough curves (BTCs) indicate higher mass recovery, less mean residence
time, and smaller dispersion of the DNA-labeled nanotracers, compared to solute dye tracers.
Importantly, travel time based tomography, using nanotracer BTCs, yields a satisfactory
hydraulic conductivity tomogram, validated by the dye tracer results and previous field
investigations. These advantages of DNA-labeled nanotracers, in comparison to traditional
solute dye tracers, make them well-suited for tomographic reservoir characterizations in fields such as hydrogeology, petroleum engineering, and geothermal energy, particularly with respect to resolving preferential flow paths or the heterogeneity of contact surfaces or by enabling source zone characterizations of dense nonaqueous phase liquids.
26.
Xia, T., E. Dontsov, Z. Chen, F. Zhang, and X.-Z. Kong, Fluid Flow in Unconventional Gas Reservoirs, Geofluids, 2018, 2018. https://doi.org/10.1155/2018/2178582 [Download] [View Abstract]Unconventional gas (including tight, shale, and coal seam gas) production has led to a drastic change of global energy landscape. The fundamental understanding of gas flow behaviours in unconventional gas reservoirs is essential to elevate the potential gas resource recovery. The behaviours of gas flow follow a chain of physicochemical processes in unconventional gas reservoirs, which can be labeled as “coupled processes” implying that one process affects the initiation and progress of another. This process chain is linked together through different disciplines, including geoscience, rock mechanics, multiphase flow, engineering chemistry, and thermodynamics, among others. Although progress on evaluation of migration, control, and recovery of unconventional gas has been achieved using mathematical models and physical experiments, the role of different fluids (eg, CH4 and other hydrocarbons, CO2, and water) in unconventional gas flow is not well understood. Filling this knowledge gap is likely to play a critical impact on raising the potential of unconventional gas resource recovery and on reducing the environmental risks.
25.
Galindo-Torres, S.A., T. Molebatsi, X.Z. Kong, A. Scheuermann, D. Bringemeier, and L. Li, Scaling solutions for connectivity and conductivity of continuous random networks, Physical Review E, Statistical, Nonlinear, and Soft Matter Physics, 92/4, pp. 041001, 2015. https://doi.org/10.1103/PhysRevE.92.041001 [Download] [View Abstract]Connectivity and conductivity of two-dimensional fracture networks (FNs), as an important type of continuous random networks, are examined systematically through Monte Carlo simulations under a variety of conditions, including different power law distributions of the fracture lengths and domain sizes. The simulation results are analyzed using analogies of the percolation theory for discrete random networks. With a characteristic length scale and conductivity scale introduced, we show that the connectivity and conductivity of FNs can be well described by universal scaling solutions. These solutions shed light on previous observations of scale-dependent FN behavior and provide a powerful method for quantifying effective bulk properties of continuous random networks.
24.
Ma, Y., X. -Z. Kong, A. Scheuermann, S. A. Galindo-Torres, D. Bringemeier, and L. Li, Microbubble transport in water-saturated porous media, Water Resources Research, 51/6, pp. 4359-4373, 2015. https://doi.org/10.1002/2014WR016019 [Download] [View Abstract]Laboratory experiments were conducted to investigate flow of discrete microbubbles through a water-saturated porous medium. During the experiments, bubbles, released from a diffuser, moved upward through a quasi-2-D flume filled with transparent water-based gelbeads and formed a distinct plume that could be well registered by a calibrated camera. Outflowing bubbles were collected on the top of the flume using volumetric burettes for flux measurements. We quantified the scaling behaviors between the gas (bubble) release rates and various characteristic parameters of the bubble plume, including plume tip velocity, plume width, and breakthrough time of the plume front. The experiments also revealed circulations of ambient pore water induced by the bubble flow. Based on a simple momentum exchange model, we showed that the relationship between the mean pore water velocity and gas release rate is consistent with the scaling solution for the bubble plume. These findings have important implications for studies of natural gas emission and air sparging, as well as fundamental research on bubble transport in porous media.
23.
Tutolo, B.M., A.J. Luhmann, X.-Z. Kong, M.O. Saar, and W.E. Seyfried Jr., CO2 sequestration in feldspar-rich sandstone: Coupled evolution of fluid chemistry, mineral reaction rates, and hydrogeochemical properties, Geochimica Et Cosmochimica Acta, 160, pp. 132-154, 2015. https://doi.org/10.1016/j.gca.2015.04.002 [Download] [View Abstract]To investigate CO2 Capture, Utilization, and Storage (CCUS) in sandstones, we performed three 150 °C flow-through experiments on K-feldspar-rich cores from the Eau Claire formation. By characterizing fluid and solid samples from these experiments using a suite of analytical techniques, we explored the coupled evolution of fluid chemistry, mineral reaction rates, and hydrogeochemical properties during CO2 sequestration in feldspar-rich sandstone. Overall, our results confirm predictions that the heightened acidity resulting from supercritical CO2 injection into feldspar-rich sandstone will dissolve primary feldspars and precipitate secondary aluminum minerals. A core through which CO2-rich deionized water was recycled for 52 days decreased in bulk permeability, exhibited generally low porosity associated with high surface area in post-experiment core sub-samples, and produced an Al hydroxide secondary mineral, such as boehmite. However, two samples subjected to ?3 day single-pass experiments run with CO2-rich, 0.94 mol/kg NaCl brines decreased in bulk permeability, showed generally elevated porosity associated with elevated surface area in post-experiment core sub-samples, and produced a phase with kaolinite-like stoichiometry. CO2-induced metal mobilization during the experiments was relatively minor and likely related to Ca mineral dissolution. Based on the relatively rapid approach to equilibrium, the relatively slow near-equilibrium reaction rates, and the minor magnitudes of permeability changes in these experiments, we conclude that CCUS systems with projected lifetimes of several decades are geochemically feasible in the feldspar-rich sandstone end-member examined here. Additionally, the observation that K-feldspar dissolution rates calculated from our whole-rock experiments are in good agreement with literature parameterizations suggests that the latter can be utilized to model CCUS in K-feldspar-rich sandstone. Finally, by performing a number of reactive transport modeling experiments to explore processes occurring during the flow-through experiments, we have found that the overall progress of feldspar hydrolysis is negligibly affected by quartz dissolution, but significantly impacted by the rates of secondary mineral precipitation and their effect on feldspar saturation state. The observations produced here are critical to the development of models of CCUS operations, yet more work, particularly in the quantification of coupled dissolution and precipitation processes, will be required in order to produce models that can accurately predict the behavior of these systems.
22.
Tutolo, B.M., X.-Z. Kong, W.E. Seyfried Jr., and M.O. Saar, High performance reactive transport simulations examining the effects of thermal, hydraulic, and chemical (THC) gradients on fluid injectivity at carbonate CCUS reservoir scales, International Journal of Greenhouse Gas Control, 39, pp. 285-301, 2015. https://doi.org/10.1016/j.ijggc.2015.05.026 [Download] [View Abstract]Carbonate minerals and CO2 are both considerably more soluble at low temperatures than they are at elevated temperatures. This inverse solubility has led a number of researchers to hypothesize that injecting low-temperature (i.e., less than the background reservoir temperature) CO2 into deep, saline reservoirs for CO2 Capture, Utilization, and Storage (CCUS) will dissolve CO2 and carbonate minerals near the injection well and subsequently exsolve and re-precipitate these phases as the fluids flow into the geothermally warm portion of the reservoir. In this study, we utilize high performance computing to examine the coupled effects of cool CO2 injection and background hydraulic head gradients on reservoir-scale mineral volume changes. We employ the fully coupled reactive transport simulator PFLOTRAN with calculations distributed over up to 800 processors to test 21 scenarios designed to represent a range of reservoir depths, hydraulic head gradients, and CO2 injection rates and temperatures. In the default simulations, 50 °C CO2 is injected at a rate of 50 kg/s into a 200 bar, 100 °C calcite or dolomite reservoir. By comparing these simulations with others run at varying conditions, we show that the effect of cool CO2 injection on reservoir-scale mineral volume changes tends to be relatively minor. We conclude that the low heat capacity of CO2 effectively prevents low-temperature CO2 injection from decreasing the temperature across large portions of the simulated carbonate reservoirs. This small thermal perturbation, combined with the low relative permeability of brine within the supercritical CO2 plume, yields limited dissolution and precipitation effects directly attributable to cool CO2 injection. Finally, we calculate that relatively high water-to-rock ratios, which may occur over much longer CCUS reservoir lifetimes or in materials with sufficiently high brine relative permeability within the supercritical CO2 plume, would be required to substantially affect injectivity through thermally-induced mineral dissolution and precipitation. Importantly, this study shows the utility of reservoir scale-reactive transport simulators for testing hypotheses and placing laboratory-scale observations into a CCUS reservoir-scale context.
21.
Tutolo, B.M., X.-Z. Kong, W.E. Seyfried Jr., and M.O. Saar, Internal consistency in aqueous geochemical data revisited: Applications to the aluminum system, Geochimica et Cosmochimica Acta, 133, pp. 216-234, 2014. https://doi.org/10.1016/j.gca.2014.02.036 [Download] [View Abstract]Internal consistency of thermodynamic data has long been considered vital for confident calculations of aqueous geochemical processes. However, an internally consistent mineral thermodynamic data set is not necessarily consistent with calculations of aqueous species thermodynamic properties due, potentially, to improper or inconsistent constraints used in the derivation process. In this study, we attempt to accommodate the need for a mineral thermodynamic data set that is internally consistent with respect to aqueous species thermodynamic properties by adapting the least squares optimization methods of Powell and Holland (1985). This adapted method allows for both the derivation of mineral thermodynamic properties from fluid chemistry measurements of solutions in equilibrium with mineral assemblages, as well as estimates of the uncertainty on the derived results. Using a large number of phase equilibria, solubility, and calorimetric measurements, we have developed a thermodynamic data set of 12 key aluminum-bearing mineral phases. These data are derived to be consistent with Na+ and K+ speciation data presented by Shock and Helgeson (1988), H4SiO4(aq) data presented by Stefánsson (2001), and the Al speciation data set presented by Tagirov and Schott (2001). Many of the constraining phase equilibrium measurements are exactly the same as those used to develop other thermodynamic data, yet our derived values tend to be quite different than some of the others’ due to our choices of reference data. The differing values of mineral thermodynamic properties have implications for calculations of Al mineral solubilities; specifically, kaolinite solubilities calculated with the developed data set are as much as 6.75 times lower and 73% greater than those calculated with Helgeson et al. (1978) and Holland and Powell (2011) data, respectively. Where possible, calculations and experimental data are compared at low T, and the disagreement between the two sources reiterates the common assertion that low-T measurements of phase equilibria and mineral solubilities in the aluminum system rarely represent equilibrium between water and well-crystallized, aluminum-bearing minerals. As an ancillary benefit of the derived data, we show that it may be combined with high precision measurements of aqueous complex association constants to derive neutral species activity coefficients in supercritical fluids. Although this contribution is specific to the aluminum system, the methods and concepts developed here can help to improve the calculation of water–rock interactions in a broad range of earth systems.
20.
Luhmann, A.J., X.-Z. Kong, B.M. Tutolo, N. Garapati, B.C. Bagley, M.O. Saar, and W.E. Seyfried Jr., Experimental dissolution of dolomite by CO2-charged brine at 100oC and 150 bar: Evolution of porosity, permeability, and reactive surface area, Chemical Geology, 380, pp. 145-160, 2014. https://doi.org/10.1016/j.chemgeo.2014.05.001 [Download] [View Abstract]Hydrothermal flow experiments of single-pass injection of CO2-charged brine were conducted on nine dolomite cores to examine fluid–rock reactions in dolomite reservoirs under geologic carbon sequestration conditions. Post-experimental X-ray computed tomography (XRCT) analysis illustrates a range of dissolution patterns, and significant increases in core bulk permeability were measured as the dolomite dissolved. Outflow fluids were below dolomite saturation, and cation concentrations decreased with time due to reductions in reactive surface area with reaction progress. To determine changes in reactive surface area, we employ a power-law relationship between reactive surface area and porosity (Luquot and Gouze, 2009). The exponent in this relationship is interpreted to be a geometrical parameter that controls the degree of surface area change per change in core porosity. Combined with XRCT reconstructions of dissolution patterns, we demonstrate that this exponent is inversely related to both the flow path diameter and tortuosity of the dissolution channel. Even though XRCT reconstructions illustrate dissolution at selected regions within each core, relatively high Ba and Mn recoveries in fluid samples suggest that dissolution occurred along the core's entire length and width. Analysis of porosity–permeability data indicates an increase in the rate of permeability enhancement per increase in porosity with reaction progress as dissolution channels lengthen along the core. Finally, we incorporate the surface area–porosity model of Luquot and Gouze (2009) with our experimentally fit parameters into TOUGHREACT to simulate experimental observations.
19.
Tutolo, B.M., A.J. Luhmann, X.-Z. Kong, M.O. Saar, and W.E. Seyfried Jr., Experimental observation of permeability changes in dolomite at CO2 sequestration conditions, Environmental Science and Technology, 48/4, pp. 2445-2452, 2014. https://doi.org/10.1021/es4036946 [Download] [View Abstract]Injection of cool CO2 into geothermally warm carbonate reservoirs for storage or geothermal energy production may lower near-well temperature and lead to mass transfer along flow paths leading away from the well. To investigate this process, a dolomite core was subjected to a 650 h, high pressure, CO2 saturated, flow-through experiment. Permeability increased from 10–15.9 to 10–15.2 m2 over the initial 216 h at 21 °C, decreased to 10–16.2 m2 over 289 h at 50 °C, largely due to thermally driven CO2 exsolution, and reached a final value of 10–16.4 m2 after 145 h at 100 °C due to continued exsolution and the onset of dolomite precipitation. Theoretical calculations show that CO2 exsolution results in a maximum pore space CO2 saturation of 0.5, and steady state relative permeabilities of CO2 and water on the order of 0.0065 and 0.1, respectively. Post-experiment imagery reveals matrix dissolution at low temperatures, and subsequent filling-in of flow passages at elevated temperature. Geochemical calculations indicate that reservoir fluids subjected to a thermal gradient may exsolve and precipitate up to 200 cm3 CO2 and 1.5 cm3 dolomite per kg of water, respectively, resulting in substantial porosity and permeability redistribution.
18.
Ma, Y., A. Scheuermann, D. Bringemeier, X.-Z. Kong, and L. Li, Size distribution measurement for densely binding bubbles via image analysis, Experiments in Fluids, 55/1860, 2014. https://doi.org/10.1007/s00348-014-1860-z [Download] [View Abstract]For densely binding bubble clusters, conventional image analysis methods are unable to provide an accurate measurement of the bubble size distribution because of the difficulties with clearly identifying the outline edges of individual bubbles. In contrast, the bright centroids of individual bubbles can be distinctly defined and thus accurately measured. By taking this advantage, we developed a new measurement method based on a linear relationship between the bubble radius and the radius of its bright centroid so to avoid the need to identify the bubble outline edges. The linear relationship and method were thoroughly tested for 2D bubble clusters in a highly binding condition and found to be effective and robust for measuring the bubble sizes.
17.
Kong, X.-Z., and M.O. Saar, Numerical study of the effects of permeability heterogeneity on density-driven convective mixing during CO2 dissolution storage, Int. J. Greenhouse Gas Control, 19, pp. 160-173, 2013. https://doi.org/10.1016/j.ijggc.2013.08.020 [Download] [View Abstract]Permanence and security of carbon dioxide (CO2) in geologic formations requires dissolution of CO2 into brine, which slightly increases the brine density. Previous studies have shown that this small increase in brine density induces convective currents, which greatly enhances the mixing efficiency and thus CO2 storage capacity and rate in the brine. Density-driven convection, in turn, is known to be largely dominated by permeability heterogeneity. This study explores the relationship between the process of density-driven convection and the permeability heterogeneity of an aquifer during CO2 dissolution storage, using high-resolution numerical simulations. While the porosity is kept constant, the heterogeneity of the aquifer is introduced through a spatially varying permeability field, characterized by the Dykstra-Parsons coefficient and the correlation length. Depending on the concentration profile of dissolved CO2, we classify the convective finger patterns as dispersive, preferential, and unbiased fingering. Our results indicate that the transition between unbiased and both preferential and dispersive fingering is mainly governed by the Dykstra-Parsons coefficient, whereas the transition between preferential and dispersive fingering is controlled by the permeability correlation length. Furthermore, we find that the CO2 dissolution flux at the top boundary will reach a time-independent steady state. Although this flux strongly correlates with permeability distribution, it generally increases with the permeability heterogeneity when the correlation length is less than the system size.
16.
Kong, X.-Z., and M.O. Saar, DBCreate: A SUPCRT92-based program for producing EQ3/6, TOUGHREACT, and GWB thermodynamic databases at user-defined T and P, Computers and Geosciences, 51, pp. 415-417, 2013. https://doi.org/10.1016/j.cageo.2012.08.004 [Download] [View Abstract]SUPCRT92 is a widely used software package for calculating the standard thermodynamic properties of minerals, gases, aqueous species, and reactions. However, it is labor-intensive and error-prone to use it directly to produce databases for geochemical modeling programs such as EQ3/6, the Geochemist's Workbench, and TOUGHREACT. DBCreate is a SUPCRT92-based software program written in FORTRAN90/95 and was developed in order to produce the required databases for these programs in a rapid and convenient way. This paper describes the overall structure of the program and provides detailed usage instructions.
15.
Luhmann, A.J., X.-Z. Kong, B.M. Tutolo, K. Ding, M.O. Saar, and W.E. Seyfried Jr., Permeability reduction produced by grain reorganization and accumulation of exsolved CO2 during geologic carbon sequestration: A new CO2 trapping mechanism, Environmental Science and Technlogy, 47/1, pp. 242-251, 2013. https://doi.org/10.1021/es3031209 [Download] [View Abstract]Carbon sequestration experiments were conducted on uncemented sediment and lithified rock from the Eau Claire Formation, which consisted primarily of K-feldspar and quartz. Cores were heated to accentuate reactivity between fluid and mineral grains and to force CO2 exsolution. Measured permeability of one sediment core ultimately reduced by 4 orders of magnitude as it was incrementally heated from 21 to 150 °C. Water-rock interaction produced some alteration, yielding sub-?m clay precipitation on K-feldspar grains in the core’s upstream end. Experimental results also revealed abundant newly formed pore space in regions of the core, and in some cases pores that were several times larger than the average grain size of the sediment. These large pores likely formed from elevated localized pressure caused by rapid CO2 exsolution within the core and/or an accumulating CO2 phase capable of pushing out surrounding sediment. CO2 filled the pores and blocked flow pathways. Comparison with a similar experiment using a solid arkose core indicates that CO2 accumulation and grain reorganization mainly contributed to permeability reduction during the heated sediment core experiment. This suggests that CO2 injection into sediments may store more CO2 and cause additional permeability reduction than is possible in lithified rock due to grain reorganization.
14.
Kong, X.-Z., M. Holzner, F. Stauffer, and W. Kinzelbach, Time-resolved 3D visualization of air injection in a liquidsaturated refractive-index-matched porous medium, Exp. Fluids, 50, pp. 1659-1670, 2011. https://doi.org/10.1007/s00348-010-1018-6 [Download] [View Abstract]The main goal of this work is to implement and validate a visualization method with a given temporal/spatial resolution to obtain the dynamic three-dimensional (3D) structure of an air plume injected into a deformable liquid-saturated porous medium. The air plume develops via continuous air injection through an orifice at the bottom of a loose packing of crushed silica grains. The packing is saturated by a glycerin-water solution having the same refractive index and placed in a rectangular glass container. By using high-speed image acquisition through laser scanning, the dynamic air plume is recorded by sequential tomographic imaging. Due to the overlap between adjacent laser sheets and the light reflection, air bubbles are multiply exposed in the imaging along the scanning direction. Four image processing methods are presented for the removal of these redundant pixels arising from multiple exposure. The respective results are discussed by comparing the reconstructed air plume volume with the injected one and by evaluating the morphological consistency of the obtained air plume. After processing, a 3D dynamic air flow pattern can be obtained, allowing a quantitative analysis of the air flow dynamics on pore-scale. In the present experimental configuration, the temporal resolution is 0.1 s and the spatial resolution is 0.17 mm in plane and about 1 mm out of plane of the laser sheet.
13.
Kong, X.-Z., W. Kinzelbach, and F. Stauffer, Compaction and size segregation in a liquid-saturated grain packing due to pulsation effect during air injection, Chem.Eng.Sci., 65, pp. 2680-2688, 2010. https://doi.org/10.1016/j.ces.2010.01.003 [Download] [View Abstract]Injecting air into two-dimensional vertical liquid-saturated assemblies of grains causes a rearrangement of the grains. The interaction of the air flow injected at the bottom with the grains and the liquid leads to a mobilization of the grains, in which air channels migrate and grain clusters undergo shearing. The channel migration comes to a stop after some time, leaving one thin and stable preferential channel for air flow. Furthermore, the grain packing is compacted due to a rearrangement process caused by the pulsating movement of air channels. The compaction process is found to obey a slow exponential growth law. Additionally, the pulsation introduces size segregation in the packing. This is visualized by a set of tracing experiments showing that the coarser grains tend to accumulate at the downstream end of the preferential air pathway. However, the pulsating strength decreases sharply as the grain size increases. Therefore no segregation was observed in the coarse packing. A stabilization process of the preferential air channel can be described by a lower bound of critical channel size assuming the validity of Hagen–Poiseuille air flow inside the channel. Nevertheless, the channel size could not exceed an upper size which is determined by the capillary instability, assuming a quasi-static equilibrium of the dilating process of the air channel.
12.
Kong, X.-Z., W. Kinzelbach, and F. Stauffer, Morphodynamics during air injection into water-saturated movable spherical granulates, Chem.Eng.Sci., 65, pp. 4652-4660, 2010. https://doi.org/10.1016/j.ces.2010.05.007 [Download] [View Abstract]Laboratory air injection experiments in a two-dimensional vertically placed cell filled with a water-saturated packing of spherical glass beads show a particular transition of air flow patterns at different length scales, tree-like fingering with pore-scale drainage, a local fluidization of beads with finger-scale channeled air flow, and an oscillating irregular channel with finger-scale air flow, where the channel is formed by pushing beads aside. The tree-like pattern shows a parabola-like growth with vertical height, while both the top and the bottom lateral width of the pattern increase linearly for the small injection rate, then stay more or less constant for further increasing injection rates. By tracing the vertical position of maximum advance of the fluidized pattern with time, the evolution of the fluidized pattern is characterized by two dynamic regimes, the pattern not reaching or reaching the injection orifice, respectively, using small and medium injection rates. As the injection rate increases further, the fluidized pattern shows up immediately after air is injected. Via physical conceptual models using local forces or pressure gradient balances, we derive a series of characteristics that describe the width of the tree-like air plume, the width of a single channel, and the starting vertical position of the fluidized pattern.
11.
Kong, X.-Z., W. Kinzelbach, and F. Stauffer, Migration of air channels: an instability of air flow in mobile saturated porous media, Chem.Eng.Sci., 64, pp. 1528-1535, 2009. https://doi.org/10.1016/j.ces.2008.12.028 [Download] [View Abstract]A set of two-dimensional laboratory visualization experiments reveals a previously unrecognized gas-flow instability in a porous medium saturated with a glycerine–water solution. The medium is a non-fixed vertically placed packing of grains of crushed fused silica glass. The interaction of the injected air flow and the medium structure leads to mobilization of the medium and an instability, which causes the air channel to migrate. This instability is dominated by a dimensionless number α, which can be interpreted as a normalization of a critical velocity with a dipole velocity for saturated conditions. The channel migration appears as a sequence of previous channels collapsing and new channels opening. The channel migration comes to a stop after some time, leaving one thin and stable channel. The process is studied by calculating the cumulated lateral movement distance of a channel and the lateral width of the area affected by the migration, both scaled by α with an empirical power of 0.25. Another dimensionless number f is defined to qualify the migration under different grain size, height of bed, and air flow rate.
10.
Stauffer, F., X.-Z. Kong, and W. Kinzelbach, A stochastic model for air injection into saturated porous media, Water Resour, 32, pp. 1180-1186, 2009. https://doi.org/10.1016/j.advwatres.2009.03.010 [Download] [View Abstract]Air injection into porous media is investigated by laboratory experiments and numerical modelling. Typical applications of air injection into a granular bed are aerated bio-filters and air sparging of aquifers. The first stage of the dynamic process consists of air injection into a fixed or a quasi-fixed water-saturated granular bed. Later stages could include stages of movable beds as well, but are not further investigated here. A series of laboratory experiments were conducted in a two-dimensional box of the size 60 cm × 38 cm × 0.55 cm consisting of glass walls and using glass beads of diameter 0.4–0.6 mm as granular material. The development of the air flow pattern was optically observed and registered using a digital video camera. The resulting transient air flow pattern can be characterized as channelled flow in a fixed porous medium with dynamic tree-like evolution behaviour. Attempts are undertaken to model the air injection process. Multiphase pore-scale modelling is currently disregarded since it is restricted to very small scales. Invasion percolation models taking into account gravity effects are usually restricted to slow processes. On the other hand a continuum-type two-phase flow modelling approach is not able to simulate the observed air flow pattern. Instead a stochastic continuum-type approach is discussed here, which incorporates pore-scale features on a subscale, relevant for the immiscible processes involved. Consequently, the physical process can be modelled in a stochastic manner only, where the single experiment represents one of many possible realizations. However, the present procedure retains realistic water and air saturation patterns and therefore produces similar finger lengths and widths as observed in the experiments. Monte Carlo type modelling leads to ensemble mean water saturation and the related variance.
9.
Wang, W.-J., X.-Z. Kong, and Z.-G. Zhu, Friction and relative energy dissipation in sheared granular materials, Phys.Rev. E, 75/041302, 2007. https://doi.org/10.1103/PhysRevE.75.041302 [Download] [View Abstract]The oscillating cylinder of a low-frequency inverted torsion pendulum is immersed into layers of noncohesive granular materials, including fine sand and glass beads. The relative energy dissipation and relative modulus of the granular system versus the amplitude and immersed depth of the oscillating cylinder are measured. A rheological model based on a mesoscopic picture is presented. The experimental results and rheological model indicate that small slides in the inhomogeneous force chains are responsible for the energy dissipation of the system, and the friction of the grains plays two different roles in the mechanical response of sheared granular material: damping the energy and enhancing the elasticity.
8.
Kong, X.-Z., M.-B. Hu, Q.-S. Wu, and Y.-H. Wu, Kinetic energy sandpile model for conical sandpile development by evolving rivers, Phys. Lett A, 348, pp. 77-81, 2006. https://doi.org/10.1016/j.physleta.2005.08.068 [Download] [View Abstract]In this Letter, a kinetic energy sandpile model, taking into account of grain inertia and the moving directions of the toppling grain, is developed and used to study the behaviour of sandpiles. In our model, the inertial effects are based on the toppling kinetic energy. The phenomenon of sandpile formation by revolving rivers is reproduced with the model, revolving velocity ω∼t^{−2/3} and ∼h^{−3/2}, where t is the simulation time and h is the height of the sandpile.
7.
Kong, X.-Z., M.-B. Hu, Q.-S. Wu, and Y.-H. Wu, Effects of bottleneck on granular convection cells and segregation, Granular Matter, 8, pp. 119-124, 2006. https://doi.org/10.1007/s10035-006-0008-0 [Download] [View Abstract]Dry glass granular material confined to a 2D-chamber convects when it is subjected to vertical sinusoidal vibrations of sufficient intensity. Effects of the container geometry on convection pattern and segregation process are studied experimentally. Here we introduce a bottleneck into the ordinary rectangular chamber, with one sidewall bended inward, characterized by λ being the ratio of the length of the bottleneck to the length of the chamber’s base. The convection roll and segregation pattern are significantly affected by λ. For λ = 0.9, two different stabilized patterns co-exist, depending on initial granular distribution. The sloping angle of the free surface to the horizontal increases with increasing λ, and reaches its saturation at λ = 0.9. The angle of the interface of the segregation region to the horizontal also increases with increasing λ.
6.
Kong, X.-Z., M.-B. Hu, Q.-S. Wu, and Y.-H. Wu, Effects of vibration frequency on intruders’ position in granular bed, Phys. Lett A, 356, pp. 267-271, 2006. https://doi.org/10.1016/j.physleta.2006.03.063 [Download] [View Abstract]In this Letter, we study the motion of multiple intruders in a vertically vibrated granular bed. From molecular dynamics simulations, it is found that the mean vertical position of the intruders, relative to the base of the container, is governed primarily by the vibration frequency for a fixed vibration acceleration. The intruders stay in the upper layer of the granular bed at low frequency, then sink into the granular bed at a certain depth as the frequency increases, but rise up again at high frequency. This implies that the mean position of the intruders in the granular bed can be controlled by decreasing or increasing the vibration frequency. A subsequent theoretical analysis is also conducted to explore the mechanism behind the phenomenon.
5.
Hu, M.-B., Q.-S. Wu, X.-Z. Kong, and Y.-H. Wu, Discharge oscillation of particles from a vertical Pipe with capillary outlet, Chinese Science Bulletin, 50, pp. 1076-1078, 2005. https://doi.org/10.1360/982005-177 [Download] [View Abstract]A new style of discharge process from a vertical open-top pipe with capillary outlet is reported. The outflux fluctuates greatly with time and the bulk condensed granular flow in the pipe shows stop-and-go motion when the filling height is above a threshold. When the filling height falls towards the threshold, led by a transitional stage, the outflux and the bulk movement become much stable. The upper surface dropping velocity variation is measured. A heuristic theory is proposed to understand the stop- and-go motion and the transitional behavior.
4.
Kong, X.-Z., M.-B. Hu, Q.-S. Wu, and Y.-H. Wu, Ring-like size segregation in vibrated cylinder with a bottleneck, Phys. Lett A, 341, pp. 278-284, 2005. https://doi.org/10.1016/j.physleta.2005.04.058 [Download] [View Abstract]In this Letter, a ring-like segregation pattern of bi-dispersed granular material in a vibrated bottleneck-cylinder is presented. The driving frequency can greatly affect the strength and structure of the convection roll and segregation pattern. The position and height of the ring (cluster of big beads) can be adjusted by altering the vibration frequency. And a heuristic theory is developed to interpret the ring's position dependence on driving frequency.
3.
Hu, M.-B., X.-Z. Kong, Q.-S. Wu, and Y.-H. Wu, Granular segregation in a multi-bottleneck container: Mobility effect, Int. J. Mod. Phys. B, 19, pp. 1793-1800, 2005. https://doi.org/10.1142/S021797920502950X [Download] [View Abstract]We investigate experimentally and via computer simulations the segregation pattern of binary granular mixtures in a vibrated container with bottlenecks. During the vibration the granular motion is more violent at the bottlenecks than at the bellies. Particles with more mobility congregate to the necks, while those with less mobility congregate to the bellies. We use discrete element simulations to reproduce the main characteristics of the experimental observations.
2.
Hu, M.-B., X.-Z. Kong, Q.-S. Wu, and Y.-H. Wu, Effects of container geometry on granular segregation pattern, Chinese Physics, 14, pp. 1793-1800, 2005. https://doi.org/10.1088/1009-1963/14/9/028 [Download] [View Abstract]In a set of vibrating quasi-two-dimensional containers with the right-hand sidewall bent inward, three new segregation patterns have been identified experimentally including a Two-Side segregation Pattern, a Left-hand Side segregation Pattern and a pattern where big particles aggregate to the upper left part of the container. In a container with small bending degree, either the two-side segregation pattern or the left-hand side segregation pattern is stable, which is determined by the initial distribution of particles.
1.
Hu, M.-B., X.-Z. Kong, Q.-S. Wu, and Z.-G. Zhu, Experimental study of energy absorption properties of granular materials under low frequency vibrations, Int. J. Mod. Phys. B., 18, pp. 2708-2712, 2004. https://doi.org/10.1142/S0217979204025956 [Download] [View Abstract]The low frequency vibration energy absorption properties of granular materials have been investigated on an Invert Torsion Pendulum (ITP). The energy absorption rate of granular material changes nonlinearly with amplitude under low frequency vibration. The frequency of ITP system increases a little with granular materials in the holding cup. The vibration frequency of ITP system does not change with time.
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PROCEEDINGS REFEREED
5.
Rangel Jurado, N., X-Z. Kong, A. Kottsova, F. Games, M. Brehme, and M.O. Saar, Investigating the chemical reactivity of the Gipskeuper and Muschelkalk formations to wet CO2 injection: A case study towards the first CCS pilot, Swiss Geoscience Meeting, 2023. [View Abstract]Carbon capture and storage (CCS) is expected to play a major role in societal attempts to reduce CO2 emissions and mitigate climate change. In parallel, CO2-based geothermal systems have been proposed as an innovative technology to couple CCS with geothermal energy extraction, therefore, increasing renewable energy production and unlocking industry-scale carbon capture, utilization, and storage (CCUS). The safe implementation and sustainability of both these technologies require a comprehensive understanding of how injected CO2 will interact with formation fluids and rocks in situ, especially under elevated pressure and temperature conditions. Whereas the role that CO2-bearing aqueous solutions play in geological reservoirs has been extensively studied, the chemical behavior of non-aqueous CO2-rich mixtures containing water has been vastly overlooked by academics and practitioners alike. In this study, we address this knowledge gap by conducting core-scale laboratory experiments that investigate the chemical reactivity of CO2-H2O mixtures, on both ends of the mutual solubility spectrum, towards reservoir and caprock lithologies. We conducted batch reactions on rock specimens from the Muschelkalk and Gipskeuper formations in Switzerland, subjecting them to interactions with wet CO2 under reservoir conditions (35 MPa, 150 °C) for approximately 500 hours. A wide range of high-resolution techniques, including scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray computed tomography (XRCT), and stable isotope analysis, were employed to characterize the evolution of petrophysical properties, morphology, and chemical composition of the samples. Furthermore, upon experiment termination, we analyzed fluid effluents using inductively coupled plasma atomic emission spectroscopy (ICP-AES) to gain insights into ion transport processes associated with dissolution reactions caused by both the aqueous and non-aqueous phases. Our results reveal that fluid-mineral interactions involving CO extsubscript{2}-rich supercritical fluids containing water are significantly less severe than those caused by aqueous solutions containing CO extsubscript{2}. Nonetheless, the existence of dissolved ions in the wet CO2 samples is evidence of ion transport processes caused by the gaseous phase that warrants further investigation. The experimental characterization of CO2-H2O mixtures under a wide range of reservoir and operating conditions represents a critical step in ensuring the reliability, long-term security, and technical feasibility of deploying CCS and CO2-based geothermal energy worldwide.
4.
Lima, M., P. Schädle, D. Vogler, M. Saar, and X.-Z. Kong, A Numerical Model for Formation Dry-out During CO2 Injection in Fractured Reservoirs Using the MOOSE Framework: Implications for CO2-based Geothermal Energy Extraction, Proceedings of the World Geothermal Congress 2020, Reykjavík, Iceland, (in press). [View Abstract]Injection of supercritical carbon dioxide (scCO2) into geological reservoirs is involved in Carbon Capture, Utilization, and Storage (CCUS), such as geological CO2 storage, and Enhanced Geothermal Systems (EGS). The potential physico-chemical interactions between the dry scCO2, the reservoir fluid, and rocks may cause formation dry-out, where mineral precipitates due to continuous evaporation of water into the scCO2 stream. This salt precipitation may impair the rock bulk permeability and cause a significant decrease in the well injectivity. Formation dry-out and the associated salt precipitation during scCO2 injection into porous media have been investigated in previous studies by means of numerical simulations and laboratory experiments. However, few studies have focused on the dry-out effects in fractured rocks in particular, where the mass transport is strongly influenced by the fracture aperture distribution. In this study, we numerically model the dry-out processes occurring during scCO2 injection into brine-saturated single fractures and evaluate the potential of salt precipitation. Fracture aperture fields are photogrammetrically determined with fracture geometries of naturally fractured granite cores from the Deep Underground Geothermal (DUG) Lab at the Grimsel Test Site (GTS), in Switzerland. We use an open-source, parallel finite element framework to numerically model two-phase flow through a 2D fracture plane. Under in-situ reservoir conditions, the brine is displaced by dry scCO2 and also evaporates into the CO2 stream. The fracture permeability is calculated with the local cubic law. Additionally, we extend the numerical model by the Young-Laplace equation to determine the aperture-based capillary pressure. Finally, as future work, the precipitation of salt will be modelled by employing a uniform mineral growth approach, where the local aperture uniformly decreases with the increase in precipitated mineral volume. The numerical simulations assist in understanding the long-term behaviour of reservoir injectivity during subsurface applications that involve scCO2 injection, including CO2-based geothermal energy extraction.
3.
Lima, M.M., P. Schädle, D. Vogler, M.O. Saar, and X.-Z. Kong, Impact of Effective Normal Stress on Capillary Pressure in a Single Natural
Fracture, European Geothermal Congress 2019, pp. 1-9, 2019. [View Abstract]Multiphase fluid flow through rock fractures occurs in many reservoir applications such as geological CO2 storage, Enhanced Geothermal Systems (EGS), nuclear waste disposal, and oil and gas production. However, constitutional relations of capillary pressure versus
fluid saturation, particularly considering the change of fracture aperture distributions under various stress conditions, are poorly understood. In this study, we use fracture geometries of naturally-fractured granodiorite cores as input for numerical simulations of two-phase brine displacement by super critical CO 2 under various effective normal stress conditions. The aperture fields are first mapped via photogrammetry, and the effective normal stresses are applied by means of a Fast Fourier Transform (FFT)-based convolution numerical method. Throughout the simulations, the capillary pressure is evaluated from the local aperture. Two approaches to obtain the capillary pressure are used for comparison: either directly using the Young-Laplace equation, or the van Genuchten equation fitted from capillary pressure-saturation relations generated using the pore-occupancy model. Analyses of the resulting CO2 injection patterns and the breakthrough times enable investigation of the relationships between the effective normal stress, flow channelling and aperture-based capillary pressures. The obtained results assist the evaluation of two-phase flow through fractures in the context of various subsurface applications.
2.
Ma, J., M.O. Saar, and X.-Z. Kong, Estimation of Effective Surface Area: A Study on Dolomite Cement Dissolution in Sandstones, Proceedings World Geothermal Congress 2020, 2019.
1.
Wu, Q.-S., M.-B. Hu, X.-Z. Kong, and Y.-H. Wu, Particle Discharge Process from a Capillary Pipe, Traffic and Granular Flow’05, pp. 193-202, 2007. https://doi.org/10.1007/978-3-540-47641-2_16 [Download] [View Abstract]The particle discharge process from a vertical open-top pipe with a capillary outlet reveals some exceptions to the common belief that the outflux oscillation results solely from dynamic arching of beads at the orifice and that the outflux is not sensitive to the filling height. With beads of a particular size range, the outflux fluctuates greatly with time and the bulk dense granular flow in the pipe shows stop-and-go motion when the filling height is above a threshold. When the filling height falls to the threshold, led by a transitional stage, the outflux and the bulk movement become stable. The dropping velocity variation of the upper surface is measured to study the bulk motion in the pipe. With a heuristic theory, we find that the granular compaction and interstitial air pressure effect are responsible for the stop-and-go oscillation and the transitional behavior.
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PROCEEDINGS NON-REFEREED
3.
Rangel Jurado, N., X-Z. Kong, A. Kottsova, M. Brehme, F. Games, and M.O. Saar, Experimental characterization of the chemical reactivity of wet scCO2 under elevated pressure and temperature conditions, Society of Core Analysts Annual Symposium , 2023. [View Abstract]CO2-Plume Geothermal (CPG) systems have been proposed as an affordable and scalable strategy to deploy Capture, Utilization, and Storage (CCUS) globally. These systems utilize CO2 to extract geothermal energy from the subsurface while ensuring its permanent sequestration in geologic formations. Unlike conventional hydrothermal systems that use water or brine, CPG utilizes pure supercritical CO2 (scCO2) or water-bearing scCO2 as the subsurface working fluid. While the thermal-hydraulic performance of CPG systems has been extensively studied, their chemical behavior remains largely unexplored due to a lack of field and experimental observations. In this study, we address this knowledge gap by investigating the chemical performance of CPG systems through core-scale laboratory experiments. We conducted batch reactions on rock specimens from the Muschelkalk and Gipskeuper formations in Switzerland, subjecting them to interactions with wet scCO2 under reservoir conditions (~35 MPa, 150 °C) for approximately 500 hours. High-resolution techniques, including scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray computed tomography (XRCT), and stable isotope analysis, were employed to characterize the evolution of petrophysical properties, morphology, and mineralogical composition. Furthermore, we analyzed fluid effluents using inductively coupled plasma optical emission spectroscopy (ICP-OES) to gain insights into ion transport processes associated with dissolution reactions. Our results indicate that fluid-mineral interactions involving CO2-rich supercritical fluids are less severe than those caused by aqueous solutions. Nonetheless, the existence of dissolved ions in the wet CO2 samples is clear evidence of ion dissociation caused by the gaseous phase that warrants further investigation. This experimental investigation provides critical insights into fluid-mineral interactions involving CO2-rich fluids and represents a crucial step in ensuring the long-term security and technical feasibility of deploying global CCS and CO2-based geothermal energy.
2.
Ahkami, M. , M.O. Saar, and X.-Z. Kong, Study on mineral precipitation in fractured porous media using Lattice-Boltzmann methods, European Geothermal Congress (EGC), Hague, Netherlands, 11-14 June 2019, 2019.
1.
Kong, X.-Z., A.M.M. Leal, and M.O. Saar, Implications of hydrothermal flow-through experiments on deep geothermal energy utilization, European Geothermal Congress 2016, 2016. [View Abstract]Utilization of underground reservoirs for geothermal energy extraction, particularly using CO2 as a working fluid, requires an in-depth understanding of fluid, solute (e.g., dissolved CO2 and minerals), and energy (heat, pressure) transport through geologic formations. Such operations necessarily perturb the chemical, thermal, and/or pressure equilibrium between native fluids and rock minerals, potentially causing mineral dissolution and/or precipitation reactions with often immense consequences for fluid, solute, and energy transport, injectivity, and/or withdrawal in/from such reservoirs. The involved physico-chemico-thermo- mechanical processes often lead to modifications of permeability, one of the most variable and important parameters in terms of reservoir fluid flow and related advective solute/reactant and heat transport. Importantly, the amount of mineral dissolution/precipitation that can cause orders of magnitude in permeability reduction can be very small, if minerals are removed or deposited in pore throats or narrow fracture apertures. This potentially has detrimental consequences for geothermal energy usage.
However, analysing, understanding, and predicting reservoir evolution and flow properties are non-trivial, as they depend on complex chemical, thermodynamic, and fluid-dynamic feedback mechanisms. To achieve these goals, it requires the integration and extrapolation of thermodynamic, kinetic, and hydrologic data from many disparate sources. The validity, consistency, and accuracy of these data- model combinations are unfortunately often incomparable due to the relative scarcity of appropriate parameterizations in the literature. Here, we present some results of hydrothermal flow-through experiments on rock core samples. During the experiments, we fixed the flow rates, confinement and outlet pore-fluid pressures, and recorded inlet pore- fluid pressure. We also analysed the outlet fluid chemistry samples throughout the experiments and imaged our rock cores before and after the flow- through experiments using X-Ray Computed Tomography (XRCT). With all these data, we are able to interpret the changes in permeability, porosity, and (reactive) surface area at the core scale.
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THESES
2.
Kong, X.-Z., Experimental investigation of air injection in saturated unconsolidated porous media, Dissertation, ETH Zurich, 128 pp., 2010. https://doi.org/10.3929/ethz-a-006246547 [Download] [View Abstract]The work described in this thesis is primarily concerned with the construction and study of laboratory scale models for the process of air injection into liquid-saturated grain packing. Experiments, both in two-dimensional (2D) and three-dimensional (3D) setups, were carried out using water-saturated packings of glass beads and/or packings of crashed fused silica glass grains saturated with a glycerin-water solution. High resolution digital images of the invasion patterns were recorded and analyzed. During air injection into a vertically-placed 2D glass bead packing saturated with water, three stages were identified, a tree-like pattern, a fluidized pattern, and a migrating single-channel pattern. The expansion of the tree-like pattern behaves in a diffusion-like manner as the air branches advance upward randomly, and finally reach a more or less constant width. The starting position of the fluidized pattern was quantitatively estimated via balancing the pressure forces between the effective stress due to the weight of the grains and the pressure resistance on the displaced fluid combined with the capillary pressure. Four dynamic regimes were distinguished: regime (i) where the fluidization stops somewhere between the top of the packing and the injection orifice, a transition regime (ii), regime (iii) where the fluidization reaches the injection orifice, and regime (iv) where the deformation of the packing appears as soon as the air is injected. A critical injection rate \(Q_{f}\) is defined to identify the transition regime. The value of \(Q_{f}\) can be determined via \(Q_{a}\), where \(Q_{a}\) is calculated as averaged flux per channel. The regime (iv) is characterized by a characteristic injection rate \(Q_{c}\), which is estimated by balancing the pressure gradient of the air flow and the overburden pressure gradient of the medium. The phenomenon of the migrating channel is measured quantitatively in two parts, before and after breakthrough. Before breakthrough, the characteristic measurements concern maximum vertical advance, maximum horizontal advance, air volumetric fraction, ratio of total surface area to volume, specific surface area of the air phase, and box-counting dimension. After breakthrough, the characteristic measurements focus on mean horizontal position of air channel, horizontal shifting distance, lateral movement distance, and lateral movement width. Before breakthrough, the maximum vertical height of the air structure approximately advances linearly with time. The maximum horizontal advance reaches a maximum value and then levels off for the rest of the time. Air volumetric fraction decreases monotonically with time, and finally levels off asymptotically to an approximate constant. In all cases, the air volumetric fraction for packings of small grains is larger than that for packings of large grains. The ratio of total surface area to volume varies in time similarly to the air volumetric fraction. However, the ratio of total surface area to volume can clearly be grouped according to the grain size, which is also true for the specific surface area of the air phase. Both can be scaled with the Bond number with a power of -0.5. After breakthrough, the migration process is studied by analyzing the mean horizontal position, horizontal shifting distance, lateral movement distance, and lateral movement width of the air channel. The results indicate that over 99% of the horizontal shifting distance is less than 10 mm. Furthermore, the its probability density function indicates that the air channel oscillates more frequently in the packing of small grains than in the packing of large grains. The interaction of the air flow with the grains and the liquid leads to a mobilization of the grains, in which air channels migrate and grain clusters undergo shearing. The channel migration comes to a stop after some time, leaving one thin and stable preferential channel for air flow. Assuming Hagen-Poiseuille’s formula to be applicable, the size of the preferential channel should exceed a lower threshold \(D_{ch}\) so that a mechanical equilibrium at the channel interface is maintained, but it should stay below an upper threshold \(D_{max}\) so that a stable air channel is sustained. A rearrangement of the grains is observed which is caused by a pulsation effect. It induces a compaction process, in which the individual grains are disassembled from the region of non-zero shear rate and then reassembled into the compacted clusters of the region of zero shear rate. It also induces a size segregation process, in which smaller grains move into the spaces beneath larger grains. By using high-speed image acquisition through laser scanning, the 3D dynamic air plume is recorded by sequential tomographic imaging. Due to the overlap between adjacent laser sheets and the light reflection, air bubbles are multiply exposed in the imaging along the scanning direction. A “curvature” method, based on a threshold on the curvature of grey-value in scanning direction, is proposed to remove the redundant pixels. The respective results are discussed by comparing the reconstructed air plume volume with the injected one and by evaluating the morphological consistency of the obtained air plume. The reconstructed air plume is further investigated with respect to its growth characteristics, such as breakthrough, air volume fraction, and air channel migration.
1.
Kong, X.-Z., Investigation on some dynamical characteristics of granular material, MSc Thesis, University of Science and Technology of China, 60 pp., 2006. [Download PDF] [View Abstract]This paper presents experimental and theoretical studies on segregation of granular media subjected to external vertical sinusoidal vibration, vibration energy absorption properties of granular materials, dynamic behaviors of sandpile formation, and the stop-and-go motion in vertical pipe flow. Results of our studies not only extend the knowledge of non-linear properties of granular media under some dynamical conditions, such as vibrating, shearing, and flowing etc, but also is a theoretical instruction in the processing, storing and transporting of granular media in applied engineering. In the experiments with vertical sinusoidal vibration of granular material in containers with bottleneck(s), new segregation patterns and convection properties were found: (1)Under the condition of two-dimensional containers with one bottleneck, with the variation of the width of bottleneck, big and small particles show ``Two Side segregation Pattern", ``Left Side segregation Pattern" and a pattern that big particles segregate to the upper-left part of the container. Furthermore, the angle of segregation interface and the angle of free-surface of granular bed follow a determinate rule, and the convection rolls of granular bed turn relatively and regularly. (2)Under the condition of three-dimensional container with one bottleneck, big particles aggregate and form a ``Ring-like Segregation" pattern, and the position and length of big particle cluster can be adjusted by changing the vibration frequency. And mechanism of segregation is proposed. (3)Under the condition of three-dimensional container with a series of bottlenecks along its vertical axis, according to the differences of ``Mobility" of each particle, particles will segregate alternantly. The simulation results of discrete element method (DEM) are in agreement with the experimental observations. The discovering of these new segregation patterns are of theoretical significance to studying the complex dynamical properties of granular materials, which also would be the engineering instruction for avoiding or enhancing segregation in the processing and transporting of granular materials. A DEM simulation of particle segregation patterns controlled by vibration frequency is carried out. It was found that: at low vibration frequency, large particles clustered on the top of the granular bed; as the frequency raised, large particles sinked into the granular assembly; at very high vibration frequency, large particles went up again. The mechanism of the transition of large particles clustering on the top---sinking---rising is studied in detail. The relation within inputted energy, void fraction and the effective restitution coefficient are found out. A Cellular Automata (CA) simulation of dynamic of sandpile formation is performed. A kinetic energy sandpile model, taking into account of grain inertia and the moving directions of the toppling grain, is developed and used to study the behaviour of sandpiles. In this model, the inertial effects are based on the toppling kinetic energy. The CA model reproduces the phenomenon of sandpile formation by revolving rivers which was found in previous experimental study in literature, and the relation between anglar speed and the height of sandpile is obtained. The simulation resluts reveal the non-symmetry of the sandpile formation and the selectivity of motion path of sand. The concepts and measuring method of internal friction are successfully applied to the measurement of low frequency vibration energy absorption properties of granular materials. An Invert Torsion Pendulum is designed to measure the energy absorption properties of granular materials under low frequency vibration using the free-attenuation mode. The vibration energy absorption of granular material decreases non-linearly with the increment of vibration amplitude under low frequency vibration. These results here can provide evidence for the understanding of some granular collective behaviors. When particles discharge from an open-top capillary pipe, it was found that, with particles of a particular size range, the outflux fluctuates greatly with time and the bulk dense granular flow in the pipe shows stop-and-go motion when the filling height is much larger than a threshold. When the filling height reduces towards the threshold, undergoing a transitional stage, the outflux and the bulk movement become much more stable. A heuristic theory taking into account of the granular compaction and interstitial air pressure effect is proposed to explain the appearing and disappearing of the stop-and-go motion. Finally, the conclusion of this paper and the prospect of further work are presented.