Marina Lima Publications

Dr. Marina Lima

Reservoir Engineer at Petrobras S.A., Former PhD Student for Geothermal Energy and Geofluids


Mailing Address
Marina Grimm Lima
Geothermal Energy & Geofluids
Institute of Geophysics
NO F 55
Sonneggstrasse 5
CH-8092 Zurich Switzerland

Email marina.mblima(at)

Dominique Ballarin Dolfin
Phone +41 44 632 3465
Email ballarin(at)


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Underlined names are links to current or past GEG members


Lima, M., H. Javanmard, D. Vogler, M.O. Saar, and X.-Z. Kong, Flow-through Drying during CO2 Injection into Brine-filled Natural Fractures: A Tale of Effective Normal Stress, International Journal of Greenhouse Gas Control, 109, pp. 103378, 2021. [Download PDF] [View Abstract]Injecting supercritical CO2 (scCO2) into brine-filled fracture-dominated reservoirs causes brine displacement and possibly evaporite precipitations that alter the fracture space. Here, we report on isothermal near-field experiments on scCO2-induced flow-through drying in a naturally fractured granodiorite specimen under effective normal stresses of 5-10 MPa, where two drying regimes are identified. A novel approach is developed to delineate the evolution of brine saturation and relative permeability from fluid production and differential pressure measurements. Under higher compressive stresses, the derived relative permeability curves indicate lower mobility of brine and higher mobility of the scCO2 phase. The derived fractional flow curves also suggest an increase in channelling and a decrease in brine displacement efficiencies under higher compressive stresses. Finally, lowering compressive stresses seems to hinder water evaporation. Our experimental results assist in understanding the behaviour of the injectivity of fractures and fracture networks during subsurface applications that involve scCO2 injection into saline formations.

Lima, M., P. Schädle, C. Green, D. Vogler, M.O. Saar, and X.-Z. Kong, Permeability Impairment and Salt Precipitation Patterns during CO2 Injection into Single Natural Brine-filled Fractures, Water Resources Research, 56/8, pp. e2020WR027213, 2020. [Download PDF] [View Abstract]Formation dry-out in fracture-dominated geological reservoirs may alter the fracture space, impair rock absolute permeability and cause a significant decrease in well injectivity. In this study, we numerically model the dry-out processes occurring during supercritical CO2 (scCO2) injection into single brine-filled fractures and evaluate the potential for salt precipitation under increasing effective normal stresses in the evaporative regime. We use an open-source, parallel finite-element framework to numerically model two-phase flow through 2-Dimensional fracture planes with aperture fields taken from naturally fractured granite cores at the Grimsel Test Site in Switzerland. Our results reveal a displacement front and a subsequent dry-out front in all simulated scenarios, where higher effective stresses caused more flow channeling, higher rates of water evaporation and larger volumes of salt precipitates. However, despite the larger salt volumes, the permeability impairment was lower at higher effective normal stresses. We conclude that the spatial distribution of the salt, precipitated in fractures with heterogeneous aperture fields, strongly affects the absolute permeability impairment caused by formation dry-out. The numerical simulations assist in understanding the behavior of the injectivity in fractures and fracture networks during subsurface applications that involve scCO2 injection into brine.

Lima, M.M., D. Vogler, L. Querci, C. Madonna, B. Hattendorf, M.O. Saar, and X.-Z. Kong, Thermally driven fracture aperture variation in naturally fractured granites, Geothermal Energy Journal, 7/1, pp. 1-23, 2019. [Download PDF] [View Abstract]Temperature variations often trigger coupled thermal, hydrological, mechanical, and chemical (THMC) processes that can significantly alter the permeability/impedance of fracture-dominated deep geological reservoirs. It is thus necessary to quantitatively explore the associated phenomena during fracture opening and closure as a result of temperature change. In this work, we report near-field experimental results of the effect of temperature on the hydraulic properties of natural fractures under stressed conditions (effective normal stresses of 5-25 MPa). Two specimens of naturally fractured granodiorite cores from the Grimsel Test Site in Switzerland were subjected to flow-through experiments with a temperature variation of 25-140 °C to characterize the evolution of fracture aperture/permeability. The fracture surfaces of the studied specimens were morphologically characterized using photogrammetry scanning. Periodic measurements of the efflux of dissolved minerals yield the net removal mass, which is correlated to the observed rates of fracture closure. Changes measured in hydraulic aperture are significant, exhibiting reductions of 20-75 % over the heating/cooling cycles. Under higher confining stresses, the effects in fracture permeability are irreversible and notably time-dependent. Thermally driven fracture aperture variation was more pronounced in the specimen with the largest mean aperture width and spatial correlation length. Gradual fracture compaction is likely controlled by thermal dilation, mechanical grinding, and pressure dissolution due to increased thermal stresses exerted over the contacting asperities, as confirmed by the analyses of hydraulic properties and efflux mass.

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Lima, M., P. Schädle, D. Vogler, M. Saar, and X.-Z. Kong, A Numerical Model for Formation Dry-out During CO2 Injection in Fractured Reservoirs Using the MOOSE Framework: Implications for CO2-based Geothermal Energy Extraction, Proceedings of the World Geothermal Congress 2020, Reykjavík, Iceland, (in press). [View Abstract]Injection of supercritical carbon dioxide (scCO2) into geological reservoirs is involved in Carbon Capture, Utilization, and Storage (CCUS), such as geological CO2 storage, and Enhanced Geothermal Systems (EGS). The potential physico-chemical interactions between the dry scCO2, the reservoir fluid, and rocks may cause formation dry-out, where mineral precipitates due to continuous evaporation of water into the scCO2 stream. This salt precipitation may impair the rock bulk permeability and cause a significant decrease in the well injectivity. Formation dry-out and the associated salt precipitation during scCO2 injection into porous media have been investigated in previous studies by means of numerical simulations and laboratory experiments. However, few studies have focused on the dry-out effects in fractured rocks in particular, where the mass transport is strongly influenced by the fracture aperture distribution. In this study, we numerically model the dry-out processes occurring during scCO2 injection into brine-saturated single fractures and evaluate the potential of salt precipitation. Fracture aperture fields are photogrammetrically determined with fracture geometries of naturally fractured granite cores from the Deep Underground Geothermal (DUG) Lab at the Grimsel Test Site (GTS), in Switzerland. We use an open-source, parallel finite element framework to numerically model two-phase flow through a 2D fracture plane. Under in-situ reservoir conditions, the brine is displaced by dry scCO2 and also evaporates into the CO2 stream. The fracture permeability is calculated with the local cubic law. Additionally, we extend the numerical model by the Young-Laplace equation to determine the aperture-based capillary pressure. Finally, as future work, the precipitation of salt will be modelled by employing a uniform mineral growth approach, where the local aperture uniformly decreases with the increase in precipitated mineral volume. The numerical simulations assist in understanding the long-term behaviour of reservoir injectivity during subsurface applications that involve scCO2 injection, including CO2-based geothermal energy extraction.

Lima, M.M., P. Schädle, D. Vogler, M.O. Saar, and X.-Z. Kong, Impact of Effective Normal Stress on Capillary Pressure in a Single Natural Fracture, European Geothermal Congress 2019, pp. 1-9, 2019. [View Abstract]Multiphase fluid flow through rock fractures occurs in many reservoir applications such as geological CO2 storage, Enhanced Geothermal Systems (EGS), nuclear waste disposal, and oil and gas production. However, constitutional relations of capillary pressure versus fluid saturation, particularly considering the change of fracture aperture distributions under various stress conditions, are poorly understood. In this study, we use fracture geometries of naturally-fractured granodiorite cores as input for numerical simulations of two-phase brine displacement by super critical CO 2 under various effective normal stress conditions. The aperture fields are first mapped via photogrammetry, and the effective normal stresses are applied by means of a Fast Fourier Transform (FFT)-based convolution numerical method. Throughout the simulations, the capillary pressure is evaluated from the local aperture. Two approaches to obtain the capillary pressure are used for comparison: either directly using the Young-Laplace equation, or the van Genuchten equation fitted from capillary pressure-saturation relations generated using the pore-occupancy model. Analyses of the resulting CO2 injection patterns and the breakthrough times enable investigation of the relationships between the effective normal stress, flow channelling and aperture-based capillary pressures. The obtained results assist the evaluation of two-phase flow through fractures in the context of various subsurface applications.

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Lima, M., Evolution of permeability of natural fractures due to THMC processes in the context of CO2-based reservoir applications, Dissertation, 242 pp., 2020. [View Abstract]As reserves decline and development costs increase, especially in frontier regions, understanding and preventing formation damage is crucial to guarantee the economic feasibility of exploitation of deep subsurface geological reservoirs. Formation damage is characterized by a zone of reduced permeability, potentially caused by coupled thermo-hydraulic-mechanical-chemical (THMC) processes that arise during typical operations, such as injection of fluids that are not preexisting in the reservoir, e.g., dry carbon dioxide. In this context, carbon dioxide injection can be considered as a perturbation to the presupposed equilibrated system. Injection of supercritical carbon dioxide (scCO2) into geological reservoirs is involved in several geoengineering activities, such as geothermal energy extraction, hydrocarbon production, and geological CO2 storage. In fractured-dominated reservoirs, THMC effects arising from scCO2 injection into brine-filled formations have a high potential of impairing the reservoir permeability due to the particularities of flow through fractures. These THMC effects act in a coupled and complex manner. Despite wide research on different effects impacting reservoir permeability, there is a need to conduct further studies, especially through laboratory experiments, to determine the hydraulic conductivity of fractures under prescribed combinations of confining stress, temperature and fluid chemical imbalance. This work focuses on fracture permeability behavior subjected to coupled THMC processes, by investigating: (1) the impact of effective normal stress on fracture absolute permeability in numerical simulations, supported by laboratory experiments, and on relative permeability curves in laboratory experiments; (2) the impact of temperature on fracture absolute permeability in laboratory experiments; and (3) the impact of mineral precipitation of fracture absolute permeability in numerical simulations. All rock specimens in this work are granodiorite specimens obtained from the Grimsel Test Site (GTS), Switzerland. Therefore, the originality of this work lies in providing results on natural fractures submitted to coupled THMC effects, which are challenging to predict but, if the morphology of the fracture is available, the investigations potentially give valuable insights. First, to evaluate the impact of effective normal stress, sigma', on fracture permeability, laboratory and numerical studies were performed. For the numerical studies, aperture fields of six naturally fractured specimens were first obtained under zero-stress conditions, via photogrammetric scans, and afterward under effective normal stress conditions of 2–30 MPa and temperatures of 25–400 oC, by means of a contact mechanics model. Both, mechanical and hydraulic apertures decreased with an increasing \sigma' and temperature, and the results show that the distributions of fracture apertures have a direct impact on the fracture permeability response. Laboratory single-phase flow-through tests conducted in a GTS fractured specimen under effective normal stress conditions of 2–15 MPa also showed decreases of fracture permeability due to increasing \sigma'. Additionally, laboratory tests were conducted to investigate the drying process of brine by scCO2 injection into another GTS fractured specimen, under conditions of 5-10 MPa effective normal stresses. A novel approach was developed to delineate the evolution of brine saturation and relative permeability from measurements of fluid production and pressure gradient across the specimen. Results from the laboratory experiments revealed lower mobility of brine and higher mobility of the scCO2 phase under higher effective normal compressive stresses. The analysis of relative permeabilities and fractional flow also suggested that higher effective normal compressive stresses increased channelling and decreased brine displacement efficiencies. Finally, lowering effective normal compressive stresses seems to hinder water evaporation. Secondly, laboratory flow-through tests on naturally-fractured granodiorite specimens were performed to investigate the impact of temperature on fracture absolute permeability. Two specimens were subjected to a constant flow rate of deionized water and pressure gradient across the fracture was measured, while step-wise and constant-rate changes in temperature were applied to the pressure cell. For different levels of confining stresses (20-40 MPa), the temperature varied from 25 oC to 140 oC, for 2 to 3 cycles, yielding decreases in absolute permeability of 20-75%. This decrease was more pronounced during the cycles subjected to higher confining stresses. The tests show hysteretic behavior during individual load cycles, indicating temperature path-dependent behavior of permeability. Chemical analysis of the effluent samples suggests that the decrease in fracture absolute permeability is caused by THMC processes such as thermal dilation, mechanical creep, and pressure dissolution, triggered by high temperatures. Thirdly, to investigate the impact of mineral precipitation on fracture permeability, a novel numerical model was implemented into the MOOSE framework to simulate the injection of scCO2 into a brine-filled heterogeneous single fracture. The numerical model captures the changes in the fracture aperture distribution due to the volume of precipitated salt, which arises from the supersaturation of brine after water evaporation into the scCO2 stream. The simulations were carried out with aperture fields under effective normal stresses of 2--10 MPa. The results indicate impairments of fracture permeability due to mineral precipitation up to 21.98%, and larger impairments were observed for the cases of lower effective normal stresses. Interestingly, despite the experienced larger permeability reductions, lower effective normal stresses promoted lower volumes of precipitated salt, relative to the initial volume, when compared to the volumes of salt observed for higher sigma'. For cases of higher effective normal stress, the precipitated salt in regions that did not impair the permeability as much as it did for the cases of lower effective normal stresses. The simulation results demonstrate the importance of considering not only the overall reduction of the fracture volume when studying formation damage in heterogeneous fractures, but also the spatial distribution of the precipitate throughout the aperture field under the considered effective normal stress state. To sum up, this thesis highlights the importance of fracture closure driven by increasing temperature and effective normal stress, as well as clogging by mineral precipitation, as these effects can compromise the long-term operation of enhanced geothermal systems or the operation of any reservoir where the operation performance depends strongly on the transmissivity of natural or stimulated fractures.

Lima, M.M., The effect of sulfate ions on the performance of smartwater flooding applied to carbonate reservoirs, MSc Thesis, University of Campinas, 197 pp., 2016. [View Abstract]The "low salinity water" technology is an enhanced oil recovery method that is gaining attention from researchers and the oil industry. For carbonate reservoirs, which are normally oil wet or mixed wet, this technique is even more attractive. Studies have shown that the sulfate ion plays a unique role on the technique, acting as a catalyzer for the multiple ion exchanges that promote the wettability alteration. The concentration of the ions Na+ and Cl-, as well as the temperature, are considered important parameters. In many cases, seawater is already an optimized water for the process. Traditionally, however, in the Brazilian pre-salt oil fields, the desulfated seawater is used as the injecting water ¿ as a precaution to avoid reservoir incrustation or souring. To justify the replacement of the injection water by seawater, substantial laboratory data using reservoir carbonate rocks are still required. The present work aims to evaluate the effect of the sulfate ion in the injection water using carbonate plugs, as well as to analyze the influence of the Na+ and Cl- ions and the temperature. At the laboratory, nine water-flooding tests, at 65°C and 100°C, and six spontaneous imbibition tests, at 65°C and 90°C, were performed with different water compositions. The water-flooding tests were divided in three groups. The first group contained four tests that were selected in order to investigate the effects of the initially chosen parameters (SO42-, Na+, Cl- and temperature). The second and third groups were elaborated because the injection rates and the rock samples¿ lithology could influence the oil recovery. Therefore, other five water-flooding tests were performed to study these new perceived variables. The results have shown that an increase in the sulfate concentration of the injection water, up to the amount present in seawater, can recover up to an additional 8% OOIP, after the injection of desulfated seawater. The effect of the non-active Na+ and Cl- ions was also observed. The influence of relatively small variations (less than an order of magnitude) of the flow capillary number on the remaining oil saturation in carbonate rocks was clearly observed, indicating a very small or even inexistent critical capillary number. It was noticed that the minimum temperature for the effect of the potential ions depends on the type of test performed. In spontaneous imbibition tests, it was not possible to distinguish the effect of increasing sulfate concentrations in water at 65°C ¿ which is in agreement with literature results. However, in the water-flooding tests, at 65°C it was already possible to notice the effect of the sulfate ion on the oil recovery. Finally, the overall results open up the suggestion to analyze the viability of changing the composition of the injection water currently being used in many Brazilian pre-salt oil fields, given the seawater’s potential of saving money by simplifying the operating plant and promoting oil production